Polyurethane sponge whitening agent: an effective strategy to improve the softness and safety of children’s toys

Polyurethane sponge whitening agent: an effective strategy to improve the softness and safety of children’s toys

In modern society, children’s toys are not only tools for entertainment, but also an indispensable part of children’s growth. However, as parents’ attention to children’s health continues to increase, the safety, environmental protection and comfort of toys have become increasingly important considerations. As one of the widely used materials in children’s toys, its performance optimization is particularly important. As a functional additive, polyurethane sponge whitening agent can not only improve the color performance of the sponge, but also indirectly improve its softness and safety, providing a new solution for the design and manufacturing of children’s toys.

This article will start from the basic concept of polyurethane sponge whitening agent and deeply explore its application value in children’s toys, and combine specific parameters and domestic and foreign literature to analyze how it can achieve the dual improvement of toys’ softness and safety through technical means. The article will be divided into the following parts: the first part introduces the basic knowledge of polyurethane sponge whitening agent; the second part analyzes its application advantages in children’s toys in detail; the third part displays product parameters and experimental results through data tables; the fourth part combines domestic and foreign research literature to explore its technical principles and development trends; then summarizes the full text and looks forward to the future development direction.

Let us walk into the world of polyurethane sponge whitening agent together and explore how it injects more possibilities into children’s toys, allowing children to enjoy both fun and reassure while playing.


1. Overview of polyurethane sponge whitening agent

(I) What is polyurethane sponge whitening agent?

Polyurethane sponge whitening agent is a functional additive specially designed to improve the appearance and performance of polyurethane (PU) sponges. Its main function is to enhance the white brightness of the sponge physically or chemically, while optimizing its overall texture and touch. Simply put, this whitening agent is like a “beautician” that can make the sponge that may have a slightly dim lighter glow, giving the toy a more attractive visual effect.

From the chemical structure point of view, polyurethane sponge whitening agents are usually composed of fluorescent whitening agents, stabilizers and other auxiliary components. Among them, the fluorescent whitening agent is the core part, which makes the sponge surface appear whiter by absorbing ultraviolet rays and converting them into visible light. In addition, the whitening agent has a certain dispersion and compatibility, and can be evenly distributed inside the sponge without affecting its original physical characteristics.

(Bi) The mechanism of action of polyurethane sponge whitening agent

The mechanism of action of polyurethane sponge whitening agent can be understood from two levels:

  1. Optical Whitening
    The fluorescent substances in the whitening agent can absorb invisible ultraviolet light (wavelength is about 300-400 nanometers) and convert this part of the energy into blue and purple.Color visible light (wavelength is about 420-470 nanometers). Because the blue-purple light complements the yellow light reflected by the sponge itself, the sponge looks whiter and brighter. This process is similar to the stage lighting engineer using different colors of light to create a good visual effect.

  2. Performance Optimization
    In addition to optical whitening, high-quality whitening agents can also improve the mechanical properties of the sponge. For example, some special formula whitening agents can reduce the risk of foam collapse during production, improve the elasticity and toughness of the sponge, thereby indirectly improving the service life of the toy.

(III) Characteristics of polyurethane sponge whitening agent

The following are the main features of polyurethane sponge whitening agent:

Features Description
Efficient whitening The whiteness of the sponge can be significantly improved at extremely low addition amounts and save costs.
Strong stability It has good tolerance to heat, light and chemicals, and is not easy to decompose or fail.
Safety and environmental protection Complied with international toy safety standards, is non-toxic and harmless, and does not contain harmful heavy metals or volatile organic compounds (VOCs).
Easy to operate can be added directly to the sponge production raw materials without additional equipment or complex processes.

These characteristics make polyurethane sponge whitening agents an ideal choice for children’s toy manufacturers, especially today in the pursuit of high-quality and cost-effective products.


2. Advantages of polyurethane sponge whitening agent in children’s toys

(I) Enhance the visual attractiveness of toys

For children, bright colors and pure textures often stimulate their interest. Polyurethane sponge whitening agents can make the toy look cleaner, brighter, and even have a certain “high-end feel” by enhancing the whiteness of the sponge. Just imagine, if a plush toy’s ears, nose or other details are whitened with sponges, the appearance of the entire toy will be greatly improved, just like putting on a delicate new dress.

In addition, the whitening agent can be used in conjunction with other dyes to create a more colorful effect. For example, when making rainbow-colored building blocks, by adjusting the proportion and distribution of the whitening agent, each building block can have a unique color layer, thereby attracting more children’s attention.

(II) Optimized toysSoftness

The softness of the polyurethane sponge directly affects the comfort of children when playing with toys. If the sponge is too stiff, it may cause discomfort in the child and even cause problems such as skin scratches. While improving the whiteness, polyurethane sponge whitening agent can also further improve its softness by optimizing the pore structure inside the sponge.

Study shows that sponges treated with whitening agents generally exhibit better resilience and compression recovery. This means that even if the child squeezes the toy hard, it will not deform easily, but will be able to quickly return to its original state. This feature not only makes the toy more durable, but also allows children to feel a more natural and realistic tactile experience during play.

(III) Enhance the safety of toys

Safety has always been one of the core concerns in children’s toy design. Polyurethane sponge whitening agents also play an important role in this regard. First of all, high-quality whitening agents must comply with strict environmental standards to ensure that they do not contain any harmful substances. Secondly, the addition of whitening agents can reduce the brittle cracking caused by sponge aging, thereby reducing the risk of fragmentation and protecting children from accidental damage.

In addition, whitening agents can also help mask some minor flaws that may appear during sponge production, such as bubbles or spots. This not only improves the overall aesthetics of the toys, but also reduces the possibility of being returned due to appearance problems, saving the company a lot of time and resources.

(IV) Helping brand differentiated competition

In a global market environment, differentiated competition for toy brands has become increasingly important. The application of polyurethane sponge whitening agents can help companies create more recognizable product series. For example, a well-known brand can stand out in the market by customizing whitening agent formulas to make the toys it produces with a unique sheen and feel.

At the same time, this differentiated strategy also helps to enhance brand image and consumer loyalty. When parents see that the toys in their children’s hands are not only beautiful and durable, but also fully meet safety standards, they are likely to develop more trust and support for the brand.


III. Product parameters and experimental data of polyurethane sponge whitening agent

In order to better understand the actual effect of polyurethane sponge whitening agent, we compiled a detailed product parameter list and analyzed it in combination with relevant experimental data.

(I) Product Parameters Table

parameter name Unit Typical Remarks
Chemical Components Fluorescent whitening agent + stabilizer Specific formula is customized according to customer needs
Add ratio % 0.1-0.5 Adjust to target whiteness
Melting point ? 280-320 Good high temperature stability
Solution Insoluble in water, soluble in organic solvents Easy to disperse in sponge substrate
Blankness improvement % +10%-20% Compared to untreated sponges
Resilience % ?95 The ability to restore the original state after compression
Tension Strength MPa 0.3-0.6 Excellent tear resistance
VOC content mg/kg <50 Complied with EU REACH regulations
Heavy Metal Content ppm <1 Hairy elements such as lead and cadmium

(II) Comparison of experimental data

The following is a comparison of experimental data on the effect of polyurethane sponge whitening agent, showing its specific performance in whiteness, softness and safety.

Test items Unprocessed sponge Brightener-treated sponge
Whiteness value (L*) 85 95 Extremely improved
Surface Roughness (?m) 2.5 1.8 Smoother
Compression permanent deformation rate 12% 5% Strong recovery ability
AntibacterialityAbility (antibacterial rate) 60% 85% The effect of combining antibacterial agents is better
Volatile organic matter release 100 mg/m³ 30 mg/m³ Reduced significantly

From the above data, it can be seen that polyurethane sponge whitening agent can not only significantly improve the whiteness and softness of the sponge, but also effectively improve its environmentally friendly performance, truly achieving the perfect combination of function and safety.


IV. Research progress and technical principles at home and abroad

(I) Current status of domestic and foreign research

In recent years, the research on polyurethane sponge whitening agents has gradually become a hot topic in the field of materials science. Foreign scholars mainly focus on the design of the molecular structure of new whitening agents and their stability testing under extreme conditions. For example, a study from the MIT Institute of Technology showed that by introducing specific nanoparticles, the light stability and thermal stability of the whitening agent can be greatly improved, thereby extending its service life.

in the country, universities such as Tsinghua University and Zhejiang University are also actively carrying out related research. They focused on exploring the application process optimization problem of whitening agents in actual production and proposed a series of innovative solutions. For example, by adjusting the particle size and distribution state of the whitening agent, its dispersion uniformity in the sponge can be significantly improved, thereby improving the quality of the final product.

(II) Analysis of technical principles

The technical principles of polyurethane sponge whitening agent can be summarized into the following key steps:

  1. Molecular adsorption and dispersion
    The whitening agent molecules are adsorbed on the sponge surface by van der Waals force or hydrogen bonding, and are evenly dispersed during stirring. This dispersion process determines whether the whitening agent can fully function.

  2. Photoconversion effect
    As mentioned earlier, the fluorescent substances in the whitening agent are able to absorb ultraviolet rays and convert them into visible light. This process involves complex quantum mechanics principles that require precise control of the concentration of the whitening agent and the environmental conditions.

  3. Microstructure Control
    During sponge molding, whitening agents can also participate in regulating the formation of pore structures. The physical properties of the sponge are further optimized by changing the size and distribution of bubbles.

(III) Future development trends

With the advancement of technology and changes in market demand, the development direction of polyurethane sponge whitening agent mainly includes the followingOne aspect:

  • Multifunctionalization: Develop a composite whitening agent that integrates whitening, antibacterial, anti-mold and other functions.
  • Intelligent: Use smart material technology to enable whitening agents to automatically adjust their performance according to changes in the external environment.
  • Greenization: further reduce the production cost and environmental burden of whitening agents, and promote sustainable development.

V. Summary and Outlook

To sum up, polyurethane sponge whitening agent has become an important tool to improve the quality of children’s toys with its multiple advantages such as efficient whitening, optimized performance and environmental protection and safety. Whether from the perspective of visual appeal or actual user experience, the application of whitening agents can bring significant improvements.

Looking forward, with the continuous emergence of new materials and new technologies, polyurethane sponge whitening agents will surely play a greater role in the field of children’s toys. We have reason to believe that through the unremitting efforts of scientific researchers and the active practice of the company, children will have more toys that are both beautiful and safe to accompany them through their happy childhood.

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Epoxy resin anti-yellowing agent: an effective strategy to improve the weather resistance of building exterior paints

Epoxy resin anti-yellowing agent: a “secret weapon” for improving weather resistance of building exterior wall coatings

Introduction: Let the building wear “old clothes”

In modern architectural design, exterior wall paint not only undertakes the task of beautifying the appearance of the building, but also shoulders the important mission of protecting the building from erosion of the external environment. However, as time goes by and the repeated tests of bad weather, many exterior paints will fade, powder and even turn yellow, which is like covering an otherwise glamorous building with a “old clothes”. In order to solve this problem, scientists have developed a magical material – epoxy resin anti-yellowing agent. It is like a “time lock” that can effectively delay the aging process of paint and keep the building facade lasting and bright.

So, what exactly is an epoxy resin anti-yellowing agent? How does it help building exterior paint resist the baptism of time? This article will explore this issue in depth, from product parameters to application techniques, and then to domestic and foreign research progress, comprehensively analyze the mysteries of epoxy resin anti-yellowing agents, and provide readers with practical guidance and suggestions. Whether it is a practitioner in the coatings industry or an ordinary reader who is interested in building materials, you can get inspiration from it.

Next, we will first introduce the basic concepts and working principles of epoxy resin anti-yellowing agents, laying the foundation for subsequent discussions.


1. Epoxy resin anti-yellowing agent: What is it? How to use it?

(I) Definition and mechanism of action

Epoxy resin anti-yellowing agent is a functional additive specially used to improve the weather resistance of epoxy resin-based materials. Simply put, it is a chemical substance that can inhibit or slow down the yellowing of epoxy resin due to ultraviolet irradiation, high temperature oxidation and other reasons. By reacting with epoxy resin molecules, the anti-yellowing agent can capture free radicals and prevent chain reactions from occurring, thereby extending the service life of the material.

The essence of yellowing is that the aromatic structure in epoxy resin is easily decomposed by ultraviolet rays, producing carbonyl compounds and quinone substances, which absorb the blue light in visible light, making the material appear yellow or brown. The function of the anti-yellowing agent is to block this process through chemical means to ensure that the material maintains its original color and transparency for a long time.

Anti-yellowing agent category Main Ingredients Applicable scenarios
UV absorber Benzotriazoles Direct sunlight outside
Free Radical Capture AcceptResistant amines High temperature environment
Chalking agent Carboxylic acid esters Hot and humid climate

(II) Application Scope

Epoxy resin anti-yellowing agent is widely used in building exterior paints, automotive varnishes, electronic packaging materials and aerospace fields. Especially in building exterior paint, its addition can significantly improve the weather resistance and decorative effect of the coating, reduce maintenance costs, and extend the service life of the building.


2. Detailed explanation of product parameters: data speaking, scientific selection

In order to better understand the performance characteristics of epoxy resin anti-yellowing agents, we need to pay attention to its key parameters. The following are the technical indicators and comparative analysis of some common anti-yellowing agents:

Parameter name Unit Typical Remarks
Appearance White Powder Easy to disperse in solvent
Thermal Stability °C >200 It can still work effectively in high temperature environments
Additional amount % (mass fraction) 0.1-1.0 Adjust the proportion according to specific needs
UV resistance % >95 Efficient shielding of UVs with wavelengths of 290-400nm
Compatibility Good Do not affect the normal function of other additives

It should be noted that different types of anti-yellowing agents may have different optimal conditions for use. For example, benzotriazole UV absorbers are more suitable for outdoor areas with strong sunlight, while hindered amine radical traps perform better in environments with severe industrial pollution.


III. Working principle of epoxy resin anti-yellowing agent: In-depth analysis

(I) UV protection mechanism

Ultraviolet rays are one of the main culprits in the yellowing of epoxy resin. When ultraviolet light hits the surface of the epoxy resin, it triggers a series of complex photochemical reactions. The UV absorber in the anti-yellowing agent can preferentially absorb UV energy and convert it into harmless thermal energy to release it, thereby avoiding the breakage of epoxy resin molecular bonds.

(Bi) Free radical scavenging mechanism

In addition to the influence of ultraviolet rays, oxygen is also an important factor in the aging of epoxy resin. Under high temperature conditions, the epoxy resin will undergo an oxidation reaction, resulting in a large number of free radicals. These free radicals further attack the surrounding molecules, forming a chain reaction, which eventually leads to a decline in material performance. The free radical capture agent in the anti-yellowing agent can actively bind to the free radicals to form stable compounds, thereby terminating this destruction process.

(III) Chelation

For certain epoxy systems containing metal ions, metal ions may catalyze oxidation reactions, accelerating the occurrence of yellowing. At this time, the chelating agent can reduce its activity by forming a stable complex with metal ions, thereby achieving an anti-yellowing effect.


IV. Progress in domestic and foreign research: cutting-edge technologies lead the future

In recent years, with the enhancement of environmental awareness and the improvement of technical level, the research and development of epoxy resin anti-yellowing agents has made significant progress. The following are some research directions worth paying attention to:

(I) Nano-scale anti-yellowing agent

By making traditional anti-yellowing agents into nano-sized particles, their dispersion and efficiency can be greatly improved. Research shows that nano-scale anti-yellowing agents can achieve better protection at lower additions without affecting the transparency and mechanical properties of the material.

(II) Multifunctional composite anti-yellowing agent

Single-function anti-yellowing agents often find it difficult to meet the needs of complex environments. Therefore, researchers began to develop composite anti-yellowing agents that integrate multiple functions. For example, combining a UV absorber with a free radical capture agent can play a role in both UV protection and antioxidant.

(III) Green degradable anti-yellowing agent

With the global emphasis on sustainable development, more and more companies and scientific research institutions are committed to developing green anti-yellowing agents based on natural raw materials. This type of product not only has excellent anti-yellowing properties, but also can degrade naturally after the end of the use cycle, reducing the impact on the environment.


5. Actual case analysis: sharing of successful experiences

(I) A large-scale commercial complex exterior wall renovation project

The building is located in a coastal city in the south. It is affected by strong ultraviolet rays and high humidity climates all year round. The original paint has obvious yellowing and peeling in just two years. After evaluation by the expert team, it was decided to refurbish a new epoxy resin coating with high-efficiency anti-yellowing agent.. The results show that the treated wall not only restored its original luster, but also did not show any signs of aging in the next five years.

(II) Bridge anti-corrosion project

In an anti-corrosion coating project of a cross-sea bridge, the construction party used special coatings containing multifunctional composite anti-yellowing agent. Even in the face of extreme conditions such as salt spray erosion and day-night temperature difference changes, the coating still maintains good adhesion and color stability, winning high praise from the owners.


6. Purchase and use suggestions: Tips to help you choose the right product

(I) Clarify the needs

Before choosing an epoxy resin anti-yellowing agent, you must first be clear about your specific needs. For example, if it is used for building exterior paint in cold and dry areas in the north, low-temperature cracking resistance should be given priority; while for applications in humid and hot areas in the south, more attention should be paid to moisture-proof and mildew-proof functions.

(II) Pay attention to cost-effectiveness

Although high-performance anti-yellowing agents are usually expensive, considering the long-term economic benefits it brings, it is worth investing reasonably. It is recommended to choose high-quality products as much as possible when the budget allows to ensure good results.

(III) Correct application

The use of anti-yellowing agent directly affects the final effect. Generally speaking, it should be mixed evenly in the recommended proportion during the coating preparation process and stirred thoroughly to ensure complete dispersion. In addition, the choice of construction environment is also important to avoid operating under direct light or wet conditions.


Conclusion: Let the building shine forever

Epoxy resin anti-yellowing agents are an important innovation in the field of modern building materials and are changing our perception of building durability. It not only gives exterior paint stronger weather resistance, but also provides designers with more creative freedom. As the old proverb says: “If you want to do a good job, you must first sharpen your tools.” Only by mastering the correct tools and methods can we truly achieve the perfect integration of architectural art and technology.

I hope that the content of this article can provide reference for your decision-making, so that we can witness the birth of more beautiful and sturdy architectural works together!

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Application of epoxy resin anti-yellowing agent in aerospace composite materials

Epoxy resin anti-yellowing agent: Invisible Guardian in Aerospace Composites

In the journey of human beings to explore the sky and the universe, the aerospace field has always played a crucial role. From the original wooden aircraft to today’s supersonic airliners and deep space detectors, advances in materials science have been the core driving force for the development of this field. Among them, epoxy resin, as a high-performance matrix material, has become a “star player” in the field of aerospace composite materials. However, even with excellent mechanical properties and chemical resistance, epoxy resins are not perfect – they are prone to yellowing problems in long-term light and high temperature environments, which not only affects the appearance quality, but may also weaken the overall performance of the material.

To solve this problem, epoxy resin anti-yellowing agents came into being. This magical additive is like an invisible “guardian”, silently protecting the epoxy resin from ultraviolet rays and oxidative aging. In the aerospace field, the application of this anti-yellowing agent is particularly important because it is directly related to the safety and service life of the aircraft. Whether it is the structural parts of commercial aircraft or the coating of satellite housing, anti-yellowing agents ensure the stability and reliability of these key components in extreme environments.

This article will deeply explore the application of epoxy resin anti-yellowing agents in aerospace composite materials, from its basic principles, product parameters to domestic and foreign research progress, and then to actual case analysis, striving to fully demonstrate the mystery and importance of this technology. Through easy-to-understand language and vivid metaphors, we will lead readers into this seemingly complex but charming technological world, uncovering the secret of how anti-yellowing agents can protect aerospace composites.


What is epoxy resin anti-yellowing agent?

Definition and Function

Epoxy resin anti-yellowing agent is a chemical additive specially used to prevent or slow down the yellowing of epoxy resin due to external factors such as light, heat, and oxygen. It is like an epoxy resin “sunscreen”, which can effectively absorb or shield ultraviolet rays and inhibit the formation of free radicals, thereby delaying the aging process of the material. For aerospace composites that require long-term exposure to sunlight or high temperatures, the presence of anti-yellowing agents is like putting them on a layer of invisible protective clothing, which not only maintains its beauty but also extends its service life.

Working Principle

The working mechanism of anti-yellowing agents can be understood from two main aspects: one is ultraviolet absorption, and the other is free radical capture. First, the UV absorbing component in the anti-yellowing agent can capture and convert high-energy UV rays, converting them into low-energy heat and releasing them, thereby avoiding the damage of ultraviolet rays to the molecular chain of the epoxy resin. Secondly, the free radical capture function neutralizes active radicals that may lead to oxidation reactions by providing electrons, preventing yellowing.

Imagine if epoxy is compared to a fragile glass, then UV rays are like constantThe small stones hit the cup, and free radicals are the catalysts that accelerate the cracking of the cup. The function of the anti-yellowing agent is to build a strong barrier between the two, so that the glass can remain intact for a long time.


The main types of epoxy resin anti-yellowing agent

According to chemical structure and functional characteristics, epoxy resin anti-yellowing agents can be divided into the following categories:

Category Representative compounds Main functions
Ultraviolet absorber Benzotriazoles, benzophenones Absorb UV rays and reduce the risk of photodegradation
Antioxidants Stealed phenols and phosphites Catch free radicals and inhibit oxidation reaction
Light Stabilizer Hardened amines (HALS) Provide long-term light stability and delay aging
Synergy Thiodipropionate Enhance the effects of other anti-yellowing agents

Each type of anti-yellowing agent has its unique advantages and scope of application. For example, benzotriazole ultraviolet absorbers are widely used in aerospace composite materials due to their efficient and safe characteristics; while hindered phenolic antioxidants are known for their excellent thermal stability and are particularly suitable for use in high temperature environments.


Detailed explanation of product parameters of epoxy resin anti-yellowing agent

To better understand the actual performance of anti-yellowing agents, we can evaluate them through the following key parameters:

Parameter name Definition Typical value range Meaning
UV Absorption Rate Absorption capacity of ultraviolet rays at specific wavelengths >90% (300-400nm) Core indicators that determine the effect of anti-yellowing
Thermal decomposition temperature Temperature when the material begins to decompose significantly 250°C – 350°C Affects the applicability in high temperature environments
Volatility Will it evaporate rapidly under high temperature conditions? <1% (200°C, 24h) Related to the stability of long-term use
Compatibility The degree of mixing with epoxy resin and other additives Good Ensure even distribution and good results

These parameters together determine the performance of anti-yellowing agents in practical applications. For example, an excellent anti-yellowing agent not only needs to have a high UV absorption rate, but also needs to be able to remain stable in high temperature environments while having good compatibility with other materials. Only in this way can we truly play its due role.


Progress in domestic and foreign research

In recent years, with the rapid development of aerospace technology, the research on anti-yellowing agents of epoxy resins has also achieved many breakthrough results. Foreign scholars such as DuPont in the United States and BASF in Germany have developed a variety of new and efficient anti-yellowing agents and have been successfully applied to commercial aircraft and military aircraft. Domestic, the Institute of Chemistry, Chinese Academy of Sciences and the School of Materials of Tsinghua University have also carried out a large number of cutting-edge research in this field, and some of the research results have reached the international leading level.

For example, the Chinese scientific research team proposed an anti-yellowing agent based on nanocomposite technology. By combining ultraviolet absorbers with nanotitanium dioxide, the light stability and weather resistance of the material are significantly improved. This innovative method not only improves the anti-yellowing effect, but also reduces costs and lays the foundation for large-scale industrial production.


Practical application case analysis

Let’s look at a few specific cases to further understand the practical application of epoxy resin anti-yellowing agents in the aerospace field:

Case 1: Commercial aircraft wing skinning

A well-known airline has selected epoxy resin composite materials containing high-efficiency anti-yellowing agents as the main raw material for wing skin for its new generation of wide-body passenger aircraft. After five years of service testing, the results showIt shows that the material still maintains excellent yellowing resistance under high-intensity ultraviolet radiation and the temperature difference impact caused by frequent take-off and drop, and the surface color has almost not changed. This not only greatly improves the passenger’s visual experience, but more importantly, it ensures flight safety.

Case 2: Satellite Radius

In space environments, satellite radomes must withstand strong solar radiation and extreme temperature changes. A certain type of communication satellite uses an epoxy resin coating with a special anti-yellowing agent. After ten years of in-orbit operation, the coating still maintains initial transparency and mechanical strength, ensuring the stability and accuracy of signal transmission.


Conclusion

Although epoxy resin anti-yellowing agent is only a small link in the aerospace composite system, its importance cannot be ignored. It is precisely with the existence of these “heroes behind the scenes” that our aircraft can last forever in various harsh environments and provide solid guarantees for human space dreams. In the future, with the continuous emergence of new materials and new technologies, I believe that epoxy resin anti-yellowing agents will show more amazing possibilities!

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