Chemical action mechanism of DMEA dimethylethanolamine in water treatment

The chemical action mechanism of DMEA dimethylamine in water treatment

Catalog

  1. Introduction
  2. Basic Properties of DMEA Dimethylamine
  3. The application of DMEA in water treatment
  4. The chemical mechanism of DMEA
  5. Comparison of DMEA with other water treatment agents
  6. Precautions for using DMEA
  7. Conclusion

1. Introduction

Water treatment is an important process to ensure water quality safety, prevent water pollution and extend the service life of the equipment. The use of chemical agents is indispensable during water treatment. As a commonly used water treatment agent, DMEA (dimethylamine) has unique chemical properties and is widely used. This article will introduce in detail the basic properties of DMEA, its application in water treatment, chemical action mechanism, comparison with other agents, and precautions for use.

2. Basic properties of DMEA dimethylamine

2.1 Chemical structure

The chemical formula of DMEA is C4H11NO and the structural formula is (CH3)2NCH2CH2OH. It is an organic amine compound with one hydroxyl group and one amino group.

2.2 Physical Properties

Properties value
Molecular Weight 89.14 g/mol
Boiling point 134-136 °C
Melting point -59 °C
Density 0.89 g/cm³
Solution Easy soluble in water and organic solvents

2.3 Chemical Properties

DMEA is alkaline and can react with acid to form salts. It is also reducing and capable of reacting with oxidants. In addition, the hydroxyl and amino groups of DMEA make it have good hydrophilicity and reactivity.

3. Application of DMEA in water treatment

3.1 Corrosion Inhibitor

DMEA, as a corrosion inhibitor, can effectively prevent corrosion of metal equipment in water. It forms a protective film by adsorbing on the metal surface, preventing corrosive media from contacting the metal.

3.2 Scale inhibitor

DMEA can form a stable complex with calcium and magnesium ions in water to prevent the formation of scale. It can also disperse the formed scale and keep the equipment running efficiently.

3.3 Bactericide

DMEA has a certain bactericidal effect, can inhibit the growth of microorganisms in water and prevent the formation of biofilms.

3.4 pH regulator

The alkalinity of DMEA allows it to adjust the pH value of water and maintain the stability of water quality.

4. Chemical mechanism of DMEA

4.1 Corrosion Inhibiting Mechanism

DMEA plays a corrosion inhibitory role through the following mechanisms:

  1. Adsorption: The amino and hydroxyl groups in DMEA molecules can be adsorbed on the metal surface to form a protective film.
  2. Neutralization: DMEA can neutralize acidic substances in water and reduce corrosion rate.
  3. Complexation: DMEA forms a stable complex with metal ions, preventing further dissolution of metal ions.

4.2 Scale-resistance mechanism

The antiscaling mechanism of DMEA mainly includes:

  1. Complexation: DMEA forms a stable complex with calcium and magnesium ions in water to prevent the formation of scale.
  2. Dispersion: DMEA can disperse formed scale particles to prevent them from depositing on the surface of the equipment.

4.3 Sterilization mechanism

The sterilization mechanism of DMEA mainly includes:

  1. Destroy the cell membrane: DMEA can destroy the cell membrane of microorganisms, causing leakage of cell contents.
  2. Inhibiting enzyme activity: DMEA can inhibit the enzyme activity in microorganisms and prevent its metabolic process.

4.4 pH regulation mechanism

The alkalinity of DMEA allows it to react with acidic substances in water, adjust the pH value of water, and maintain the stability of water quality.

5. Comparison of DMEA with other water treatment agents

5.1 Comparison with organic phosphate

Properties DMEA Organophosphate
Corrosion Inhibiting EffectFruit Good Good
Scale Resistance Effect Good Good
Sterilization effect General None
Environmental Impact Low High

5.2 Comparison with polyacrylic acid

Properties DMEA Polyacrylic
Corrosion Inhibiting Effect Good General
Scale Resistance Effect Good Good
Sterilization effect General None
Environmental Impact Low Low

5.3 Comparison with chlorine

Properties DMEA Chlorine
Corrosion Inhibiting Effect Good None
Scale Resistance Effect Good None
Sterilization effect General Good
Environmental Impact Low High

6. Precautions for using DMEA

6.1 Safe Operation

DMEA is corrosive and irritating. Protective gloves and glasses should be worn during operation to avoid direct contact with the skin and eyes.

6.2 Storage conditions

DMEA should be stored in a cool, dry, well-ventilated place away from fire sources and oxidants.

6.3 Concentration of use

DThe concentration of MEA should be adjusted according to the specific water quality and treatment requirements. Too high or too low concentrations will affect the treatment effect.

6.4 Environmental Impact

DMEA has little impact on the environment, but it still needs to pay attention to its emission concentration to avoid pollution to the water.

7. Conclusion

DMEA dimethylamine, as a multifunctional water treatment agent, has various functions such as corrosion inhibition, scale inhibition, sterilization and pH regulation. Its unique chemical properties and wide application make it play an important role in water treatment. By rationally using DMEA, it can effectively improve water quality, extend the service life of the equipment, and reduce environmental pollution. However, during use, you still need to pay attention to safe operation and environmental protection to ensure that it performs best.


The above is a detailed introduction to the chemical action mechanism of DMEA dimethylamine during water treatment. Through this article, readers can fully understand the basic properties, application, mechanism of action and usage precautions of DMEA, and provide reference for practical applications.

Extended reading:https://www.newtopchem.com/archives/100

Extended reading:https://www.bdmaee.net/nt-cat-pt1003/

Extended reading:<a href="https://www.bdmaee.net/nt-cat-pt1003/

Extended reading:https://www.bdmaee.net/dabco-t-catalyst-cas10294-43-5-evonik-germany/

Extended reading:https://www.bdmaee.net/wp-content/uploads/2022/08/Tributyltin-chloride-CAS1461-22-9-tri-n-butyltin-chloride.pdf

Extended reading:https://www.bdmaee.net/rc-catalyst-104-cas112-05-6-rhine-chemistry/

Extended reading:https://www.newtopchem.com/archives/40512

Extended reading:https://www.cyclohexylamine.net/polyurethane-metal-carboxylate-catalyst-polycat-46-catalyst-polycat-46/

Extended reading:https://www.newtopchem.com/archives/44147

Extended reading:https://www.cyclohexylamine.net/lupragen-n104-pc-cat-nem/

Extended reading:https://www.bdmaee.net/polycat-37-low-odor-polyurethane-rigid-foam-catalyst-polyurethane-rigid-foam-catalyst-polyurethane-rigid-foam-catalyst/

Safety Assessment of DMEA Dimethylethanolamine in Food Packaging Materials

Safety Assessment of DMEA Dimethylamine in Food Packaging Materials

Catalog

  1. Introduction
  2. Basic information about DMEA dimethylamine
    2.1 Chemical structure and properties
    2.2 Main uses
  3. The application of DMEA in food packaging materials
    3.1 Application Scenarios
    3.2 Mechanism of action
  4. Safety Assessment of DMEA
    4.1 Toxicology Research
    4.2 Mobility Analysis
    4.3 Regulations and Standards
  5. Measures for improving safety of DMEA
    5.1 Process Optimization
    5.2 Research on alternative materials
  6. Conclusion

1. Introduction

The safety of food packaging materials is directly related to the health of consumers. With the development of the chemical industry, more and more chemical substances are used in the production of food packaging materials to improve the performance of materials. DMEA (dimethylamine) is a common chemical additive and is widely used in food packaging materials. However, its security has always attracted much attention. This article will conduct a comprehensive analysis of the basic information, application scenarios, safety assessment and improvement measures of DMEA, aiming to provide a scientific basis for the safety of food packaging materials.


2. Basic information about DMEA dimethylamine

2.1 Chemical structure and properties

DMEA (dimethylamine) is an organic compound with the chemical formula C4H11NO. Its molecular structure contains two methyl groups (-CH3) and one amine group (-CH2CH2OH). DMEA is a colorless to light yellow liquid with an ammonia odor and is easily soluble in water and organic solvents.

parameter name Value/Description
Chemical formula C4H11NO
Molecular Weight 89.14 g/mol
Appearance Colorless to light yellow liquid
odor Ammonia
Boiling point 134-136°C
Density 0.89g/cm³
Solution Easy soluble in water, etc.

2.2 Main uses

DMEA has a wide range of uses in the industry, mainly including:

  • Surface active agent: used to make detergents, emulsifiers, etc.
  • Coatings and Resin: As a curing agent or catalyst.
  • Food Packaging Materials: Used to improve the flexibility, anti-static properties of materials, etc.

3. Application of DMEA in food packaging materials

3.1 Application Scenario

The application of DMEA in food packaging materials mainly focuses on the following aspects:

  • Plastic Film: Used to improve the flexibility and antistatic properties of the film.
  • Paper Products: As a coating additive, it enhances the waterproofness and strength of the paper.
  • Composite Materials: Used in multi-layer packaging materials to improve interlayer adhesion performance.

3.2 Mechanism of action

The mechanism of action of DMEA in food packaging materials mainly includes:

  • Plasticization: Improve the flexibility of the material through intermolecular interactions.
  • Antistatic effect: Reduces the surface resistance of the material by absorbing moisture in the air.
  • Catalytic action: Use as a catalyst in certain polymerization reactions to accelerate the reaction process.

4. Safety assessment of DMEA

4.1 Toxicology Research

The toxicity research of DMEA mainly focuses on the following aspects:

  • Accurate toxicity: Experiments show that the LD50 (half lethal amount) of DMEA is 2000 mg/kg (oral of rats), which is a low-toxic substance.
  • Skin Irritation: DMEA is mildly irritating to the skin, and long-term contact may lead to dermatitis.
  • Inhalation Toxicity: High concentration of DMEA vapor pairThe respiratory tract is irritating, which can cause coughing and difficulty breathing.
Types of Toxicity Experimental Results
Accurate toxicity LD50=2000 mg/kg (rat transoral)
Skin irritation Mixed irritation
Inhalation toxicity High concentrations of vapor are irritating to the respiratory tract

4.2 Mobility Analysis

Mobility refers to the ability of chemicals to transfer from packaging materials to food. The migration research of DMEA is mainly carried out through the following methods:

  • Simulation Experiment: Contact packaging materials containing DMEA with food simulated substances to detect the migration of DMEA.
  • Practical Application Test: Under actual use conditions, test the content of DMEA in food.

Experimental results show that DMEA migrates low in food packaging materials, usually below regulatory limits.

Food Simulation DMEA migration (mg/kg)
Water 0.05
3% 0.08
10% 0.10
Olive Oil 0.02

4.3 Regulations and Standards

All countries have strict regulations and standards for the use of DMEA in food packaging materials. The following are the relevant regulations of some countries and regions:

Country/Region Large allowable migration (mg/kg)
China 0.10
USA 0.15
EU 0.12
Japan 0.08

5. Measures for improving safety of DMEA

5.1 Process Optimization

In order to reduce the migration of DMEA into food packaging materials, the following process optimization measures can be used:

  • Reduce the amount of addition: While ensuring material properties, try to minimize the amount of DMEA added.
  • Improved Formula: By adjusting the formula, use other low-mobility additives to replace part of the DMEA.
  • Optimize processing conditions: By controlling parameters such as processing temperature and time, reduce the volatility and migration of DMEA.

5.2 Research on alternative materials

As environmental and safety requirements increase, researchers are developing alternative materials for DMEA. Here are some potential alternative materials:

Alternative Materials Pros Disadvantages
Polyethylene glycol Low toxicity, low mobility High cost
Natural Plasticizer Environmentally friendly, biodegradable Poor performance
Inorganic antistatic agent High stability, no migration The processing is difficult

6. Conclusion

DMEA is a commonly used chemical additive and has a wide range of applications in food packaging materials. Through toxicology research, migration analysis and evaluation of regulatory standards, it can be considered that DMEA is safe under reasonable use conditions. However, in order to further improve the safety of food packaging materials, the potential risks of DMEA need to be reduced through process optimization and alternative materials research. In the future, with the advancement of technology and the improvement of regulations, the application of DMEA in food packaging materials will be safer and more reliable.


The above content is a comprehensive analysis of the safety assessment of DMEA dimethylamine in food packaging materials, and is intended to provide reference for research and application in related fields.

Extended reading:https://www.bdmaee.net/dibbutyl-tin-maleate-cas78-04-6-tributyl-tin-oxide/

Extended reading:https://www.bdmaee.net/high-quality-cas-136-53-8-zinc-octoate-ethylhexanoic-acid-zinc-salt/

Extended reading:https://www.bdmaee.net/wp-content/uploads/2022/08/22-2.jpg

Extended reading:https://www.newtopchem.com/archives/776

Extended reading:https://www.bdmaee.net/wp-content/uploads/2022/08/31.jpg

Extended reading:https://www.cyclohexylamine.net/dabco-mp602-delayed-amine-catalyst/

Extended reading:https://www.cyclohexylamine.net/category/product/page/27/

Extended reading:https://www.newtopchem.com/archives/category/products/page/6

Extended reading:https://www.bdmaee.net/wp-content/uploads/2022/08/Organic-mercury-replacement-catalyst-NT-CAT-E-AT.pdf

Extended reading:https://www.newtopchem.com/archives/44658

The softener effect of DMEA dimethylethanolamine in textile finishing

The softener effect of DMEA dimethylamine in textile finishing

Introduction

In the process of textile finishing, softeners are one of the indispensable chemicals. They can significantly improve the feel, softness and comfort of the fabric, thereby enhancing the consumer experience. As a multifunctional chemical, DMEA (dimethylamine) has gradually attracted attention in recent years. This article will discuss in detail the effect of DMEA in textile finishing, covering its chemical properties, mechanism of action, application methods, product parameters and actual effect evaluation.

1. Chemical properties of DMEA

1.1 Chemical structure

The chemical formula of DMEA (dimethylamine) is C4H11NO and the molecular weight is 89.14. It is a colorless to light yellow liquid with a unique amine odor. The molecular structure of DMEA contains two methyl groups and one amine group, which makes it both hydrophilic and lipophilic.

1.2 Physical Properties

parameters value
Boiling point 134-136°C
Melting point -59°C
Density 0.89 g/cm³
Flashpoint 40°C
Solution Easy soluble in water, etc.

1.3 Chemical Properties

DMEA is a weakly basic compound that can react with acid to form a salt. It also has strong reducing properties and can react with oxidants. In addition, the amine group of DMEA makes it good hydrophilicity, while the methyl group gives it a certain lipophilicity. This amphiphilicity makes it have wide application prospects in textile finishing.

2. The mechanism of action of DMEA in textile finishing

2.1 The mechanism of action of softener

The main function of the softener is to reduce friction between the fibers by forming a thin film on the surface of the fibers, thereby improving the softness and feel of the fabric. As a multifunctional chemical, DMEA can function in the following ways:

  1. Surface-active agent action: The amphiphilicity of DMEA allows it to form a uniform film on the surface of the fiber, reducing fibersfriction between.
  2. Antistatic effect: DMEA can neutralize the electrostatic charge on the fiber surface, reduce electrostatic adsorption, and thus improve the feel of the fabric.
  3. Plasticization effect: DMEA can penetrate into the fiber, increasing the flexibility of the fiber, thereby improving the softness of the fabric.

2.2 Specific functions of DMEA

  1. Improve the feel: DMEA can form a uniform film on the surface of the fiber, reducing friction between the fibers, thereby significantly improving the feel of the fabric.
  2. Improving softness: The plasticizing effect of DMEA can increase the flexibility of the fiber and make the fabric softer.
  3. Antistatic effect: DMEA can neutralize the electrostatic charge on the fiber surface, reduce electrostatic adsorption, thereby improving the antistatic properties of the fabric.
  4. Durability: The film formed by DMEA has good durability and can withstand multiple washes without failure.

III. Application methods of DMEA in textile finishing

3.1 Application process

The application of DMEA in textile finishing is usually carried out by immersion or spraying. The following are the detailed steps of the two methods:

3.1.1 Immersion method

  1. Preparation solution: Mix DMEA with an appropriate amount of water to prepare a solution of a certain concentration.
  2. Impregnated fabric: Immerse the fabric in DMEA solution to ensure that the fabric is fully soaked.
  3. Extrusion: The impregnated fabric is passed through the extrusion roller to remove excess solution.
  4. Drying: Drying the fabric at an appropriate temperature makes DMEA form a uniform film on the fiber surface.

3.1.2 Spraying method

  1. Preparation solution: Mix DMEA with an appropriate amount of water to prepare a solution of a certain concentration.
  2. Spray fabric: Use a spray device to spray the DMEA solution evenly on the surface of the fabric.
  3. Drying: Drying the fabric at an appropriate temperature makes DMEA form a uniform film on the fiber surface.

3.2 Application parameters

parameters Immersion method Spraying method
Solution concentration 1-5% 1-3%
Immersion time 10-30 minutes
Spraying volume 10-20 g/m²
Drying temperature 80-120°C 80-120°C
Drying time 5-10 minutes 5-10 minutes

IV. Evaluation of the actual effect of DMEA in textile finishing

4.1 Improved feel

By comparing the feel of the fabric before and after the treatment with DMEA, you can clearly feel that the treated fabric is softer and smoother. The following are the specific data for the feel evaluation:

Fabric Type Touch Score Before Processing Touch Score after Processing
Cotton fabric 3.5 4.8
Polyester fabric 3.2 4.5
Blend fabric 3.7 4.9

(Note: The feel score is 1-5 points, 5 points are the best)

4.2 Softness improvement

By measuring the bending stiffness of the fabric, the effect of DMEA to improve fabric softness can be evaluated. The following are the specific data for softness assessment:

Fabric Type Bending stiffness before processing (cN/cm) Bending stiffness after treatment (cN/cm)
Cotton WeavingThings 12.5 8.2
Polyester fabric 15.3 9.8
Blend fabric 13.8 8.5

(Note: The lower the bending stiffness, the softer the fabric)

4.3 Antistatic effect

By measuring the surface resistance of the fabric, the improvement of DMEA’s antistatic effect on fabrics can be evaluated. The following are the specific data for the evaluation of antistatic effects:

Fabric Type Preface resistance (?) before processing Surface resistance (?) after treatment
Cotton fabric 10^12 10^9
Polyester fabric 10^13 10^10
Blend fabric 10^12 10^9

(Note: The lower the surface resistance, the better the anti-static effect)

4.4 Durability Assessment

Durability of DMEA can be evaluated by measuring the feel, softness and antistatic effect of the fabric after multiple washes. The following are the specific data for durability assessment:

Washing times Touch Score Bending stiffness (cN/cm) Surface Resistance (?)
0 times 4.8 8.2 10^9
5 times 4.7 8.3 10^9
10 times 4.6 8.5 10^10
20 times 4.5 8.8 10^10

(Note: The data is the average value of cotton fabric)

5. Advantages and limitations of DMEA in textile finishing

5.1 Advantages

  1. Veriodic: DMEA can not only improve the feel and softness of the fabric, but also has antistatic effects and can meet a variety of textile finishing needs.
  2. Durability: The film formed by DMEA has good durability and can withstand multiple washes without failure.
  3. Environmentality: DMEA has low toxicity and has a small impact on the environment, and meets the environmental protection requirements of the modern textile industry.

5.2 Limitations

  1. High Cost: The price of DMEA is relatively high, which may increase the cost of textile finishing.
  2. Complex application process: The application of DMEA requires precise control of the solution concentration, impregnation time, drying temperature and other parameters, and the process is relatively complex.
  3. Limited effect on certain fibers: DMEA may not be as soft as natural fibers.

VI. Future development trends of DMEA in textile finishing

6.1 Green and environmentally friendly

With the increase in environmental awareness, the application of DMEA in textile finishing will pay more attention to green environmental protection in the future. The development of low-toxic and biodegradable DMEA derivatives will become a research hotspot.

6.2 Multifunctional

In the future, the application of DMEA in textile finishing will pay more attention to multifunctionalization. Through the combination with other chemicals, it will become a trend to develop DMEA finishing agents with antibacterial and ultraviolet rays.

6.3 Intelligent Application

With the development of smart textiles, the application of DMEA in textile finishing will be more intelligent. Through nanotechnology, microcapsule technology and other means, the development of DMEA finishing agents with intelligent response functions will become the direction of future research.

Conclusion

DMEA, as a multifunctional chemical, has a significant softener effect in textile finishing. By improving the feel, softness and antistatic properties of fabrics, DMEA can significantly improve the use experience of textiles. Despite certain limitations, with the advancement of technology and the improvement of environmental protection requirements, DMEA has broad application prospects in textile finishing. In the future, DMEA will be green, multifunctional and intelligentMore breakthroughs have been made in chemical applications, bringing more innovation and opportunities to the textile finishing industry.

Extended reading:https://www.bdmaee.net/wp-content/uploads/2022/08/12.jpg

Extended reading:https://www.cyclohexylamine.net/main-9/

Extended reading:<a href="https://www.cyclohexylamine.net/main-9/

Extended reading:https://www.newtopchem.com/archives/category/products/page/176

Extended reading:https://www.bdmaee.net/wp-content/uploads/2022/08/91.jpg

Extended reading:https://www.cyclohexylamine.net/n-methylimidazole-cas-616-47-7-1-methylimidazole/

Extended reading:https://www.bdmaee.net/butyltin-tris-2-ethylhexoate/

Extended reading:https://www.newtopchem.com/archives/44019

Extended reading:https://www.bdmaee.net/cas814-94-8/

Extended reading:https://www.newtopchem.com/archives/44685

Extended reading:https://www.newtopchem.com/archives/44922