Application of polyurethane foam amine catalyst in high-performance sports soles

Application of polyurethane foam amine catalyst in high-performance sports soles

Introduction

As people’s requirements for sports shoes continue to improve, polyurethane (PU) foam material has gradually become the first choice for high-performance sports soles due to its excellent elasticity, wear resistance and lightness. In the production process of polyurethane foam, the selection and use of catalysts have a crucial impact on the performance of the final product. This article will conduct in-depth discussion on the application of polyurethane foam amine catalyst in high-performance sports soles, covering its working principle, product parameters, performance advantages and practical application cases.

1. Basic concepts of polyurethane foam

1.1 Definition of polyurethane foam

Polyurethane foam is a polymer material produced by chemical reactions of polyols, isocyanates, catalysts, foaming agents and other additives. Its structure consists of hard and soft segments, which provide strength and rigidity, while the soft segments impart elasticity and flexibility to the material.

1.2 Classification of polyurethane foam

Depending on the foaming method, polyurethane foam can be divided into open-cell foam and closed-cell foam. Open-cell foam has good breathability and sound absorption properties, while closed-cell foam has high strength and thermal insulation properties. In high-performance sports soles, open-cell foam is often used to provide better cushioning and breathability.

2. The role of polyurethane foam amine catalyst

2.1 Basic functions of catalysts

Catalytics play a crucial role in the formation of polyurethane foam. They can accelerate the reaction between polyols and isocyanates and control the reaction rate, thereby affecting the density, hardness, elasticity and other properties of the foam.

2.2 Advantages of amine catalysts

Amine catalysts are a commonly used polyurethane foam catalysts, which have the following advantages:

  • High efficiency: Amines catalysts can significantly accelerate the reaction rate and shorten the production cycle.
  • Controlability: By adjusting the type and dosage of amine catalysts, the performance of the foam can be accurately controlled.
  • Environmentality: Some amine catalysts have low volatility and low toxicity, and meet environmental protection requirements.

2.3 Types of amine catalysts

Common amine catalysts include:

Catalytic Types Main Ingredients Features
Term amine catalyst Triethylamine, dimethylamine Efficient and low price
Ququaternary ammonium salt catalyst Tetramethylammonium hydroxide High activity, low volatility
Metal Organocatalyst Organic tin, organic bismuth High selectivity, environmental protection

III. Application of polyurethane foam amine catalyst in high-performance sports soles

3.1 Requirements for high-performance sports soles

High-performance sports soles require the following characteristics:

  • cushioning: effectively absorbs impact force and protects the feet.
  • Elasticity: Provides good rebound performance and enhances sports performance.
  • Abrasion Resistance: Extend the service life of the sole.
  • Lightness: Reduce the weight of the shoes and improve the comfort of wearing.
  • Breathability: Keep your feet dry and prevent odors.

3.2 Application of amine catalysts in sole production

In the production of high-performance sports soles, amine catalysts are mainly used in the following aspects:

3.2.1 Control reaction rate

By selecting the appropriate amine catalyst, the reaction rate of the polyol and isocyanate can be precisely controlled, thereby obtaining the ideal foam structure and performance. For example, the use of high-efficiency tertiary amine catalysts can shorten foaming time and improve production efficiency.

3.2.2 Adjusting foam density

The type and amount of amine catalyst have a significant impact on the density of the foam. By adjusting the ratio of the catalyst, foam of different densities can be obtained to meet the needs of different sports soles. For example, high-density foam is suitable for soles that require high strength and wear resistance, while low-density foam is suitable for soles that require lightweight and cushioning.

3.2.3 Improve foam performance

Amine catalysts can also improve the elasticity, wear resistance and breathability of foams. For example, the use of quaternary ammonium catalysts can improve the elasticity and resilience of the foam, and the use of metal organic catalysts can enhance the wear resistance and durability of the foam.

3.3 Practical Application Cases

The following are some practical application cases that demonstrate the specific application of amine catalysts in high-performance sports soles:

3.3.1 Case 1: Basketball soles

Basketball sports have high requirements for cushioning and elasticity of the soles. By using high-efficiency tertiary aminesThe chemical agent can generate highly elastic and high-cushioning polyurethane foam in a short period of time, effectively absorbing the impact force in basketball and protecting athletes’ feet.

3.3.2 Case 2: Running soles

The running soles need to be good lightweight and breathable. By using low-volatile quaternary ammonium catalysts, low-density, high-breathability polyurethane foam can be generated, reducing the weight of shoes, keeping the feet dry and improving running comfort.

3.3.3 Case 3: Mountaineering soles

Hiking soles need to be high strength and wear resistance. By using metal organic catalysts, high-density and high-strength polyurethane foam can be generated, which enhances the wear resistance and durability of the sole and adapts to complex mountain environments.

IV. Product parameters of polyurethane foam amine catalyst

4.1 Catalyst selection

When selecting an amine catalyst, the following parameters need to be considered:

parameters Instructions
Activity The higher the activity of the catalyst, the faster the reaction rate
Volatility Low volatile catalysts are more environmentally friendly
Toxicity Safety low toxic catalysts
Price Price factors affect production costs

4.2 Dosage of catalyst

The amount of catalyst used has a significant impact on foam performance. Generally, the amount of catalyst is between 0.1% and 1%, and the specific amount needs to be adjusted according to production conditions and product requirements.

4.3 Catalyst ratio

In actual production, a combination of multiple catalysts is usually used to equilibrium the reaction rate and foam properties. For example, a high-efficiency tertiary amine catalyst can be used in combination with a low-volatile quaternary ammonium catalyst to obtain ideal reaction rates and foam properties.

V. Performance advantages of polyurethane foam amine catalyst

5.1 Improve production efficiency

The high efficiency of amine catalysts can significantly shorten foaming time, improve production efficiency, and reduce production costs.

5.2 Improve product performance

By precisely controlling the type and amount of catalyst, ideal foam performance can be obtained and meet the requirements of high-performance sports soles.

5.3 Environmental protection and safety

Some amine catalysts have low volatility and low toxicity, meet environmental protection and safety requirements, and reduceHazards to the environment and the human body.

VI. Future development trends

6.1 Research and development of new catalysts

With the continuous improvement of environmental protection and safety requirements, more low-volatility and low-toxicity new amine catalysts will be developed in the future to meet market demand.

6.2 Intelligent production

By introducing intelligent production technology, precise control and automated addition of catalysts can be achieved, and production efficiency and product consistency can be improved.

6.3 Multifunctional development

The future amine catalysts will not only be limited to catalytic functions, but will also have other functions, such as antibacterial and mildew, further improving the performance of sports soles.

Conclusion

The application of polyurethane foam amine catalyst in high-performance sports soles is of great significance. By rationally selecting and using amine catalysts, the cushioning, elasticity, wear resistance and lightness of sports shoes can be significantly improved, and the needs of different sports scenarios can be met. In the future, with the research and development of new catalysts and the introduction of intelligent production, the application of polyurethane foam amine catalysts in high-performance sports soles will be more extensive and in-depth.

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New uses of DMEA dimethylethanolamine in solvent-free coating systems: balance between environmental protection and high efficiency

New uses of DMEA dimethylamine in solvent-free coating systems: a balance between environmental protection and high efficiency

Introduction

As the global environmental awareness increases, the coatings industry is facing unprecedented challenges. Traditional solvent-based coatings release large amounts of volatile organic compounds (VOCs) during production and use, which not only cause pollution to the environment, but also pose a threat to human health. Therefore, the development of environmentally friendly coatings has become an important direction in the industry. As an environmentally friendly coating, solvent-free coatings are gradually favored by the market due to their advantages of low VOCs emissions and high efficiency performance. As a multifunctional additive, DMEA (dimethylamine) has shown unique advantages in solvent-free coating systems. This article will discuss in detail the new use of DMEA in solvent-free coatings and analyze its balance between environmental protection and high efficiency.

1. Basic characteristics of DMEA

1.1 Chemical structure and properties

DMEA (dimethylamine) is an organic compound with the chemical formula C4H11NO. It is a colorless to light yellow liquid with typical properties of amine compounds such as basic, hydrophilic and reactive. The molecular structure of DMEA contains a hydroxyl group (-OH) and an amino group (-NH2), which makes it have multiple functions in coating systems.

1.2 Product parameters

parameter name Value/Description
Chemical formula C4H11NO
Molecular Weight 89.14 g/mol
Appearance Colorless to light yellow liquid
Density 0.89 g/cm³
Boiling point 134-136°C
Flashpoint 40°C
Solution Easy soluble in organic solvents such as water, alcohols, ethers
pH value (1% aqueous solution) 11.5

1.3 Functional Characteristics

DMEA mainly has the following functions in coating systems:

  • Nelasticizer:DMEA can neutralize the acidic components in the coating, adjust the pH value of the system, and improve the stability of the coating.
  • Catalytics: DMEA can promote certain chemical reactions, such as the curing reaction of epoxy resins, and improve the curing efficiency of the coating.
  • Dispersant: DMEA can improve the dispersion of pigments and fillers, and improve the uniformity and gloss of the paint.
  • Plasticizer: DMEA can increase the flexibility of the paint and improve the mechanical properties of the coating.

2. Advantages and challenges of solvent-free coatings

2.1 Advantages of solvent-free coatings

Solvent-free coating refers to the uniform dispersion or dissolving of coating components in the system by physical or chemical methods without using organic solvents. Its main advantages include:

  • Environmentality: Solvent-free coatings contain almost no VOCs, reducing environmental pollution.
  • Safety: Solvent-free coatings reduce the risk of fire and explosion during production and use.
  • High efficiency: Solvent-free coatings usually have a high solids content, high coating efficiency, and reduce the number of coatings.
  • Durability: Coatings formed by solvent-free coatings usually have good weather resistance, chemical resistance and mechanical properties.

2.2 Challenges of solvent-free coatings

Although solvent-free coatings have many advantages, they still face some challenges in their practical applications:

  • Viscosity Control: Solvent-free coatings have high viscosity and are difficult to construct, requiring special construction equipment and technology.
  • Currency Rate: The curing rate of solvent-free coatings is slower, which affects production efficiency.
  • Cost: The raw materials and production costs of solvent-free coatings are relatively high, which limits its marketing promotion.

III. Application of DMEA in solvent-free coatings

3.1 Application as a neutralizer

In solvent-free coatings, DMEA as a neutralizer can adjust the pH value of the system and improve the stability of the coating. For example, in an epoxy resin system, DMEA can neutralize the acidic components in the resin to prevent gelation of the resin during storage. In addition, DMEA can neutralize the acidic catalyst in the coating and extend the application period of the coating.

3.1.1 Application Cases

Coating Type DMEA addition amount (%) Effect Description
Epoxy resin coating 0.5-1.0 Improve the stability of the coating and extend the applicable period
Polyurethane coating 0.3-0.8 Adjust pH value to improve coating gloss
Acrylic Paints 0.2-0.5 Nelastic acidic ingredients to prevent gelation

3.2 Application as a catalyst

DMEA can also be used as a catalyst in solvent-free coatings to promote the progress of certain chemical reactions. For example, in the curing reaction of epoxy resin, DMEA can accelerate the reaction between the resin and the curing agent and improve the curing efficiency of the coating. In addition, DMEA can also promote the reaction between isocyanate and hydroxyl groups in polyurethane coatings, and shorten the drying time of the coating.

3.2.1 Application Cases

Coating Type DMEA addition amount (%) Effect Description
Epoxy resin coating 0.2-0.5 Accelerate the curing reaction and improve production efficiency
Polyurethane coating 0.1-0.3 Promote isocyanate reaction and shorten drying time
Acrylic Paints 0.1-0.2 Improve the hardness of the coating and improve wear resistance

3.3 Application as a dispersant

DMEA can also act as a dispersant in solvent-free coatings to improve the dispersion of pigments and fillers. Through the dispersion of DMEA, the pigments and fillers in the coating can be evenly dispersed in the system, improving the uniformity and gloss of the coating. In addition, DMEA can prevent pigments and fillers from settled during storage, extending the storage stability of the paint.

3.3.1 Application Cases

Coating Type DMEA addition amount (%) Effect Description
Epoxy resin coating 0.3-0.7 Improve pigment dispersion and improve coating gloss
Polyurethane coating 0.2-0.5 Prevent filler settlement and extend storage stability
Acrylic Paints 0.1-0.3 Improve paint uniformity and improve the appearance of the coating

3.4 Application as a plasticizer

DMEA can also be used as a plasticizer in solvent-free coatings to increase the flexibility of the coating and improve the mechanical properties of the coating film. Through the plasticization of DMEA, the coating formed by the coating after curing has good flexibility and impact resistance, and is suitable for occasions where high mechanical properties are required.

3.4.1 Application Cases

Coating Type DMEA addition amount (%) Effect Description
Epoxy resin coating 0.5-1.0 Improve the flexibility of the coating and improve impact resistance
Polyurethane coating 0.3-0.8 Increase the elasticity of the coating and improve wear resistance
Acrylic Paints 0.2-0.5 Improve the ductility of the coating and improve crack resistance

IV. Environmental protection and efficient balance of DMEA in solvent-free coatings

4.1 Environmental protection

The application of DMEA in solvent-free coatings has significantly improved the environmental protection of the coatings. First, DMEA itself is a low toxic compound, and its use does not cause significant harm to the environment and human health. Secondly, as a neutralizing agent, catalyst, dispersing agent and plasticizer, DMEA can reduce the use of harmful substances in the coating and reduce the VOCs emissions of the coating. In addition, DMEA can improve the stability of the paint, reduce the waste of paint during storage and use, and further reduce the impact on the environment.

4.2 Efficiency

The application of DMEA in solvent-free coatings also significantly improves the efficiency of the coatings. first, DMEA as a catalyst can accelerate the curing reaction of the coating and improve production efficiency. Secondly, DMEA as a dispersant can improve the uniformity and gloss of the paint and improve the construction efficiency of the paint. In addition, DMEA as a plasticizer can improve the mechanical properties of the coating film, extend the service life of the coating, reduce the frequency of the coating replacement, and further improve the economicality of the coating.

4.3 Equilibrium

The application of DMEA in solvent-free coatings achieves a balance between environmental protection and high efficiency. Through the multifunctional effect of DMEA, solvent-free coatings improve the construction efficiency and usage performance of the coating while maintaining low VOCs emissions. This balance not only meets the requirements of environmental protection regulations, but also improves the market competitiveness of coatings and promotes the sustainable development of the coating industry.

V. Future Outlook of DMEA in Solvent-Free Coatings

5.1 Technological Innovation

With the continuous development of coating technology, DMEA will be more widely used in solvent-free coatings. In the future, DMEA may combine with other functional additives to develop more high-performance solvent-free coating products. For example, DMEA can be combined with nanomaterials to improve the wear and weather resistance of coatings; DMEA can also be combined with bio-based materials to develop more environmentally friendly coating products.

5.2 Marketing

As the increasing strict environmental regulations, the market demand for solvent-free coatings will continue to increase. As a multifunctional additive, DMEA will play an important role in the marketing of solvent-free coatings. In the future, the production cost of DMEA may be further reduced, making its application in solvent-free coatings more economical and feasible. In addition, DMEA’s environmental protection and efficiency will also attract the attention of more paint companies and promote the popularization of solvent-free paint market.

5.3 Sustainable Development

The application of DMEA in solvent-free coatings is in line with the concept of sustainable development. Through the multifunctional effect of DMEA, solvent-free coatings maintain environmental protection while improving the efficiency and economicality of the coating. In the future, DMEA will continue to play an important role in the coatings industry and promote the coatings industry to develop in a more environmentally friendly, efficient and sustainable direction.

Conclusion

DMEA (dimethylamine) as a multifunctional additive shows unique advantages in solvent-free coating systems. Through the neutralization, catalytic, dispersing and plasticizing effects of DMEA, solvent-free coatings improve the construction efficiency and use performance of the coating while maintaining low VOCs emissions. The application of DMEA in solvent-free coatings has achieved a balance between environmental protection and high efficiency, and has promoted the sustainable development of the coating industry. In the future, with the continuous innovation of technology and the continuous promotion of the market, DMEA will be more widely used in solvent-free coatings, bringing more opportunities and challenges to the coating industry.

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How to use DMEA dimethylethanolamine to improve paint adhesion and weather resistance

How to use DMEA dimethylamine to improve paint adhesion and weather resistance

Catalog

  1. Introduction
  2. Introduction to DMEA Dimethylamine
  3. The application of DMEA in paint
  4. Mechanisms for improving paint adhesion
  5. Mechanisms for improving paint weather resistance
  6. Product parameters and performance
  7. Practical application cases
  8. Conclusion

1. Introduction

As a common surface coating material, paint is widely used in construction, automobile, furniture and other fields. The performance of the paint directly affects the service life and appearance of the coating. Adhesion and weather resistance are two important indicators for measuring paint performance. This article will explain in detail how to use DMEA (dimethylamine) to improve the adhesion and weather resistance of paints.

2. Introduction to DMEA Dimethylamine

DMEA (dimethylamine) is an organic compound with the chemical formula C4H11NO. It is a colorless and transparent liquid with typical properties of amine compounds such as basic, hydrophilic and reactive. DMEA is widely used in chemical industry, medicine, coatings and other fields.

2.1 Physical and chemical properties

Properties value
Molecular Weight 89.14 g/mol
Boiling point 134-136 °C
Density 0.89 g/cm³
Flashpoint 40 °C
Solution Easy soluble in water,

2.2 Main uses

  • As a neutralizer and catalyst
  • For the synthesis of surfactants
  • As a coating additive

3. Application of DMEA in paint

The application of DMEA in paint is mainly reflected in the following aspects:

3.1 Neutralizer

DMEA can act as a neutralizer to adjust the pH value of the paint to keep it within a suitable range, thereby improving the stability and construction performance of the paint.

3.2 Catalyst

DMEA can be used as a catalyst to accelerate the curing process of paint, shorten drying time and improve production efficiency.

3.3 Surfactant

DMEA can be used as a surfactant to improve the wetting and dispersion of paint, so that pigments and fillers are evenly distributed in the paint film, and improve the uniformity and gloss of the coating.

4. Mechanism to improve paint adhesion

The adhesion of paint refers to the bonding force between the coating and the substrate. Good adhesion prevents the coating from peeling and blistering, extending the life of the coating. DMEA improves the adhesion of paint through the following mechanisms:

4.1 Improve wettability

As a surfactant, DMEA can reduce the surface tension of the paint and improve its wettability to the substrate. The improvement of wettability allows the paint to penetrate better into the micropores of the substrate, enhancing the mechanical bonding of the coating to the substrate.

4.2 Enhanced chemical bonding

The amine group in DMEA can react chemically with functional groups such as hydroxyl groups and carboxyl groups on the surface of the substrate to form chemical bonds. This chemical bond is stronger than pure physical adsorption, significantly improving the adhesion of the coating.

4.3 Adjust pH

DMEA, as a neutralizer, can adjust the pH of the paint to match the surface charge of the substrate. Adjusting pH value can reduce electrostatic repulsion between the coating and the substrate and enhance the bonding force between the two.

5. Mechanism for improving paint weather resistance

Weather resistance refers to the ability of the coating to resist natural factors such as ultraviolet rays, humidity, and temperature in an outdoor environment. DMEA improves the weather resistance of paints through the following mechanisms:

5.1 Antioxidant effect

The amino groups in DMEA have antioxidant effects, which can capture free radicals and prevent oxidative degradation of resins and pigments in paint. The enhanced antioxidant effect can extend the life of the coating and maintain its color and luster.

5.2 Anti-UV rays

DMEA can absorb ultraviolet rays and reduce the damage to paint by ultraviolet rays. Ultraviolet rays are one of the main factors that cause coating aging. The anti-ultraviolet effect of DMEA can effectively delay the aging process of the coating.

5.3 Adjust moisture balance

DMEA can adjust the moisture balance in the paint to prevent the coating from cracking, peeling and other problems due to excessive or too little moisture. Adjustment of moisture balance can improve the stability and durability of the coating.

6. Product parameters and performance

The following are typical product parameters and performance of DMEA in paint:

6.1 Product parameters

parameters value
Appearance Colorless transparent liquid
Purity ?99%
pH value 10-12
Density 0.89 g/cm³
Boiling point 134-136 °C
Flashpoint 40 °C

6.2 Performance indicators

Performance value
Adhesion ?5 MPa
Weather resistance ?1000 hours
Drying time ?2 hours
Gloss ?90%
Hardness ?2H

7. Practical application cases

7.1 Building exterior wall coating

Adding DMEA to building exterior paint can significantly improve the adhesion and weather resistance of the coating. After practical application testing, after 5 years of use in outdoor environments, the coating remains intact without obvious peeling or fading.

7.2 Automotive Paint

Adding DMEA to automotive coatings can improve the coating’s UV resistance and oxidation resistance. After practical application tests, after 3 years of parking outdoors with DMEA, the color and gloss of the coating remained good, and there was no obvious sign of aging.

7.3 Furniture paint

Adding DMEA to furniture coatings can enhance the adhesion and wear resistance of the coating. After practical application tests, after 2 years of use, the coating has no obvious wear or peeling of the furniture paint with DMEA, and maintains a good appearance.

8. Conclusion

DMEA dimethylamine, as a multifunctional additive, has significant advantages in the application of paint. Through mechanisms such as improving wettability, enhancing chemical bonding, and adjusting pH, DMEA can effectively improve the adhesion of paint. Through mechanisms such as antioxidant, anti-UV rays, and regulating moisture balance, DMEA can significantly improve the weather resistance of paints. Practical application cases show that the paint with DMEA has a wide range of application prospects in the fields of construction, automobile, furniture, etc.

Rational use of DMEA can significantly improve the performance of paint, extend the service life of the coating, and reduce maintenance costs. I hope that the introduction of this article can provide valuable reference for practitioners in related fields.

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