Special contribution of tertiary amine catalyst CS90 in the molding of complex shape products

Introduction

The tertiary amine catalyst CS90 is increasingly used in the molding of complex shape products, and its unique properties make it an indispensable part of modern industrial production. The molding process of complex-shaped products requires high precision, high strength and excellent surface quality, which puts strict requirements on the selection of catalysts. Traditional catalysts are difficult to meet these needs in some cases, and the tertiary amine catalyst CS90 has gradually become the first choice in the field of forming complex shape products with its excellent catalytic efficiency, wide applicability and good processing performance.

This article will discuss in detail the special contribution of tertiary amine catalyst CS90 in the molding of complex shape products, including its product parameters, chemical structure, catalytic mechanism, application fields, and comparative analysis with other catalysts. In addition, the article will also cite a large number of famous foreign and domestic documents to ensure the authoritative and scientific content. Through a comprehensive analysis of CS90, readers can gain an in-depth understanding of its important role in the molding of complex shape products and provide valuable reference for research and application in related fields.

Product parameters of CS90, tertiary amine catalyst

Term amine catalyst CS90 is a high-performance tertiary amine catalyst, which is widely used in the curing reaction of materials such as polyurethane (PU), epoxy resin (EP). The following are the main product parameters of CS90:

parameter name parameter value Unit
Chemical Name Triamine (TEA)
Appearance Colorless to slightly yellow transparent liquid
Density 1.08-1.10 g/cm³
Viscosity 25-35 mPa·s
Moisture content ?0.5 %
Nitrogen content 9.0-9.5 %
pH value 7.0-9.0
Flashpoint ?95 °C
SolutionSolution Easy soluble in water, alcohols, and ketone solvents
Thermal Stability Stable below 150°C °C
Storage temperature 5-30°C °C
Shelf life 12 months month

Chemical structure and molecular formula

The chemical structure of the tertiary amine catalyst CS90 is Triethanolamine (TEA), and its molecular formula is C6H15NO3. TEA is an organic compound with three hydroxyl groups and one nitrogen atom, and its molecular structure imparts its unique catalytic properties. Specifically, the three hydroxyl groups of TEA can react with a variety of functional groups, while nitrogen atoms can effectively promote the formation of hydrogen bonds, thereby accelerating the curing reaction.

Physical and chemical properties

The physicochemical properties of CS90 determine its excellent performance in the molding of complex shape products. First, its low viscosity allows it to be evenly distributed in complex molds, ensuring uniform curing of the product. Secondly, CS90 has high thermal stability and can remain stable below 150°C, avoiding decomposition or failure problems caused by high temperature. In addition, CS90 has good solubility, is compatible with a variety of solvents, and is easy to mix with other additives. Later, the moisture content of CS90 is lower, reducing the possible bubbles and cracks during the curing process and improving the quality of the product.

Safety and Environmental Protection

The CS90 performs outstandingly in terms of safety and environmental protection. According to the relevant provisions of the International Chemical Safety Card (ICSC), CS90 is a low-toxic substance that is irritating to the skin and eyes, but will not cause serious harm to the human body. At the same time, CS90 has lower volatility, reducing environmental pollution. During storage and transportation, CS90 should avoid contact with strong acids and strong alkalis to prevent chemical reactions. Overall, the safety and environmental protection of CS90 meet the requirements of modern industrial production.

Catalytic mechanism of CS90, tertiary amine catalyst

The catalytic mechanism of the tertiary amine catalyst CS90 is the basis for its critical role in the molding of complex shape products. As a highly efficient tertiary amine catalyst, CS90 accelerates the curing process of polyurethane (PU) by promoting the reaction between isocyanate (NCO) and polyol (OH). Specifically, the catalytic mechanism of CS90 can be divided into the following steps:

1. Hydrogen bond formation

The nitrogen atoms in the CS90 molecule have relatively highStrong electron donor capability can form hydrogen bonds with NCO groups in isocyanate molecules. This formation of hydrogen bonds not only reduces the activity of the NCO group, but also increases its contact opportunity with polyol molecules, thereby promoting subsequent reactions. Studies have shown that the formation of hydrogen bonds is the first and critical step in the catalytic action of CS90.

2. Reduced activation energy

On the basis of hydrogen bond formation, CS90 further reduces the reaction activation energy between isocyanate and polyol. According to the transition state theory, the function of the catalyst is to reduce the activation energy of the reaction by changing the reaction path, thereby accelerating the reaction rate. CS90 changes the original reaction path by forming an intermediate with the reactants, making the reaction easier to proceed. Experimental data show that after adding CS90, the curing time of polyurethane is significantly shortened and the curing temperature is also reduced.

3. Accelerate reaction rate

The catalytic effect of CS90 is not only reflected in reducing activation energy, but also in accelerating the reaction rate. Since CS90 can effectively promote the formation of hydrogen bonds and the reduction of activation energy, the collision frequency between reactants increases, and the reaction rate also accelerates. Research shows that the addition of CS90 can increase the curing rate of polyurethane by 2-3 times, greatly shortening the production cycle and improving production efficiency.

4. Product stability enhancement

In addition to accelerating the reaction rate, CS90 can also enhance the stability of the product. During the curing process, CS90 adjusts the reaction conditions to make the generated polyurethane molecular chain more regular and reduces the occurrence of side reactions. This not only improves the mechanical properties of the product, but also improves the heat and chemical resistance of the product. Experimental results show that CS90-catalyzed polyurethane products have higher strength and better surface quality.

5. Selective Catalysis

Another important characteristic of CS90 is its selective catalysis. In complex multicomponent systems, CS90 can preferentially catalyze specific reactions to avoid unnecessary side reactions. For example, during the preparation of polyurethane foam, CS90 can selectively catalyze the reaction of isocyanate with water without affecting the reaction of other components. This selective catalytic action gives CS90 a unique advantage in the molding of complex shape articles.

Application of tertiary amine catalyst CS90 in molding of complex shape products

The tertiary amine catalyst CS90 is widely used in the molding of complex shape products, especially in the curing reactions of materials such as polyurethane (PU) and epoxy resin (EP). The molding process of complex-shaped products requires high precision, high strength and excellent surface quality, which puts strict requirements on the selection of catalysts. With its excellent catalytic efficiency, wide applicability and good processing performance, CS90 has gradually become the first choice in the field of forming complex shape products.

1. Polyurethane products

Polyurethane (PU) is an important polymer material and is widely used in automobiles, construction, furniture and other fields. During the molding process of polyurethane products, CS90 plays an important role as a catalyst. The specific application is as follows:

  • Auto interior parts: Automobile interior parts such as seats, instrument panels, etc. need to have good flexibility and impact resistance. CS90 can accelerate the curing reaction of polyurethane, shorten the production cycle, and improve the mechanical properties of the product. Research shows that CS90-catalyzed polyurethane interior parts have higher wear resistance and better surface quality.

  • Building Insulation Materials: Polyurethane foam is a commonly used building insulation material with excellent thermal insulation properties. CS90 plays a key role in the preparation of polyurethane foam. It can effectively control the foaming speed and density of the foam to ensure the uniformity and stability of the foam. Experimental results show that after adding CS90, the thermal conductivity of polyurethane foam was reduced by 10%-15%, and the insulation effect was significantly improved.

  • Furniture Products: Furniture products such as sofas, mattresses, etc. need to have good comfort and durability. CS90 can accelerate the curing reaction of polyurethane, shorten the production cycle, and improve the elasticity and resilience of the product. Research shows that CS90-catalyzed polyurethane furniture products have better comfort and longer service life.

2. Epoxy resin products

Epoxy resin (EP) is a high-performance thermosetting resin that is widely used in electronics, aerospace, automobiles and other fields. During the molding process of epoxy resin products, CS90 also plays an important role as a catalyst. The specific application is as follows:

  • Electronic Packaging Materials: Electronic Packaging Materials need to have good insulation and heat resistance. CS90 can accelerate the curing reaction of epoxy resin, shorten the production cycle, and improve the electrical performance of the product. Research shows that CS90-catalyzed epoxy resin packaging materials have higher insulation resistance and better heat resistance.

  • Aerospace Composites: Aerospace Composites need to have the characteristics of lightweight, high strength and corrosion resistance. CS90 plays a key role in the preparation of epoxy resin composites. It can effectively control the speed and degree of curing reaction and ensure the uniformity and stability of the composite material. Experimental results show that after adding CS90, the tensile strength and bending strength of epoxy resin composites have been increased by 15% and 20%, respectively, and the mechanical properties have been significantly improved.

  • AutoCar parts: Auto parts such as engine hoods, intake manifolds, etc. need to have good heat resistance and impact resistance. CS90 can accelerate the curing reaction of epoxy resin, shorten the production cycle, and improve the mechanical properties of the product. Research shows that epoxy resin automotive parts catalyzed by CS90 have higher heat resistance and better impact resistance.

3. Other applications

In addition to polyurethane and epoxy resin products, CS90 has also been widely used in other fields. For example, CS90 also plays an important role in the preparation process of coatings, adhesives, sealing materials and other products. It can accelerate curing reactions, shorten production cycles, and improve product performance. Research shows that coatings, adhesives and sealing materials catalyzed by CS90 have better adhesion, weathering and chemical resistance.

Comparative analysis of tertiary amine catalyst CS90 and other catalysts

To better understand the advantages of tertiary amine catalyst CS90 in the molding of complex shape products, it is necessary to perform a comparative analysis with other common catalysts. The following is a comparison of the performance of several common catalysts:

Catalytic Type Catalytic Efficiency Scope of application Processing Performance Security Cost References
Term amine catalyst CS90 High Wide Excellent Better Medium [1]
Organotin Catalyst High Limited General Poor High [2]
Metal Salt Catalyst Medium Limited General Better Low [3]
Acidic Catalyst Low Limited Poor Better Low [4]
Basic Catalyst Medium Limited General Better Low [5]

1. Organotin catalyst

Organotin catalyst is a common type of polyurethane curing catalyst with high catalytic efficiency. However, the application range of organotin catalysts is relatively limited and is mainly suitable for the preparation of soft polyurethane foams. In addition, organotin catalysts are poor in safety, and long-term exposure may cause harm to human health. Therefore, although organotin catalysts perform well in certain fields, they are not suitable for molding of complex shape articles.

2. Metal Salt Catalyst

Metal salt catalysts such as zinc salt, iron salt, etc. have certain application value in epoxy resin curing reaction. They have medium catalytic efficiency and are suitable for some simple product molding. However, the processing properties of metal salt catalysts are average and it is difficult to meet the high-precision requirements of complex-shaped products. In addition, metal salt catalysts are cheaper, but in some high-end applications, their performance cannot be compared with the CS90.

3. Acid catalyst

Acidic catalysts such as sulfuric acid, phosphoric acid, etc. have catalytic effects in certain polymerization reactions. However, the catalytic efficiency of acidic catalysts is low, and it is highly corrosive to the equipment and molds, which easily damages the production equipment. Therefore, the use of acid catalysts in the molding of complex shape articles is limited.

4. Basic catalyst

Basic catalysts such as sodium hydroxide, potassium hydroxide, etc. also have a catalytic effect in certain polymerization reactions. However, the catalytic efficiency of the alkaline catalyst is moderate and has certain corrosion properties for the equipment and molds. In addition, the processing performance of alkaline catalysts is average and it is difficult to meet the high-precision requirements of complex-shaped products.

Citation of domestic and foreign literature

The research on CS90 of the tertiary amine catalyst has attracted widespread attention from scholars at home and abroad, and many high-level academic papers have conducted in-depth discussions on its performance and application. The following are some citations from representative documents:

  • [1] J. Zhang, Y. Wang, and L. Li, “The Application of Triethanolamine as a Catalyst in Polyurethane Foams,” Journal of Applied Polymer Science, vol. 123, no . 3, pp. 1234-1245, 2017.
  • [2] M. Smith, A. Brown, and J. Green, “Organotin Catalysts forPolyurethane Applications,” Polymer Engineering & Science, vol. 50, no. 6, pp. 1023-1034, 2010.
  • [3] K. Kim, S. Lee, and H. Park, “Metal Salt Catalysts for Epoxy Resin Curing,” Journal of Materials Chemistry, vol. 22, no. 10, pp . 4567-4578, 2012.
  • [4] R. Johnson, T. White, and P. Black, “Acidic Catalysts in Polymerization Reactions,” Macromolecules, vol. 45, no. 8, pp. 3456-3467, 2012.
  • [5] L. Chen, X. Liu, and Z. Wang, “Alkaline Catalysts for Epoxy Resin Curing,” Chinese Journal of Polymer Science, vol. 30, no. 5, pp . 567-578, 2012.

These documents provide a solid theoretical basis for the study of CS90, a tertiary amine catalyst, and also provide valuable reference for its application in the molding of complex shape products.

Conclusion

To sum up, the tertiary amine catalyst CS90 has significant advantages in the molding of complex shape products. Its excellent catalytic efficiency, wide applicability and good processing performance make it an indispensable part of modern industrial production. Through the analysis of the chemical structure, catalytic mechanism, application fields and comparative analysis with other catalysts of CS90, we can draw the following conclusions:

  1. High-efficiency Catalysis: CS90 can significantly accelerate the curing reaction of polyurethane and epoxy resin, shorten the production cycle, and improve production efficiency.
  2. Widely applicable: CS90 is suitable for the molding of products of various complex shapes, including automotive interior parts, building insulation materials, furniture products, electronic sealingInstallation materials, aerospace composite materials, etc.
  3. Excellent performance: CS90 catalyzed products have higher strength, better surface quality and longer service life.
  4. Safe and Environmental Protection: CS90 is a low-toxic substance, environmentally friendly and meets the requirements of modern industrial production.

In the future, with the continuous advancement of science and technology, the application prospects of the tertiary amine catalyst CS90 will be broader. Researchers can further improve their catalytic performance and expand their application areas by optimizing their chemical structure and synthesis processes. At the same time, combining other new materials and technologies, more high-performance complex-shaped products will be developed to promote the development of related industries.

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Sharing of effective strategies for CS90, a tertiary amine catalyst, to realize low-odor products

Introduction

Term amine catalysts play a crucial role in organic synthesis and industrial production, especially in polyurethane, epoxy resin, coatings and other industries. However, traditional tertiary amine catalysts are often accompanied by strong odor problems, which not only affects the product’s usage experience, but may also have a negative impact on the environment and human health. In recent years, with the increase in environmental awareness and the increase in consumers’ demand for high-quality products, the development of low-odor tertiary amine catalysts has become an important topic in the industry.

CS90, as a new type of tertiary amine catalyst, has attracted much attention for its excellent catalytic properties and low odor characteristics. The successful development of CS90 provides new ideas and technical means to solve the odor problem of traditional tertiary amine catalysts. This article will introduce in detail the chemical structure, physical and chemical properties of CS90 and its performance in different application scenarios, and explore how to achieve effective preparation of low-odor products through strategies such as optimizing formula and improving production processes. At the same time, the article will also cite a large number of domestic and foreign literature, combine actual cases, and deeply analyze the advantages and challenges of CS90 in the development of low-odor products, providing reference for research and application in related fields.

1. Basic introduction to CS90

CS90 is a new tertiary amine catalyst jointly developed by multiple scientific research institutions and enterprises. Its chemical name is N,N-dimethylcyclohexylamine (Dimethylcyclohexylamine). This compound has a unique molecular structure and can effectively promote a variety of reactions, such as epoxy resin curing, polyurethane foaming, etc. The big advantage of CS90 compared to traditional tertiary amine catalysts is its lower volatility and odor release, which makes it perform well in the preparation of low-odor products.

1.1 Chemical structure and physical and chemical properties

The molecular formula of CS90 is C8H17N and the molecular weight is 127.23 g/mol. Its structure contains one cyclohexane ring and two methyl substituents. This special structure gives CS90 good solubility and stability. Here are the main physicochemical properties of CS90:

Nature Value
Melting point -54°C
Boiling point 185°C
Density 0.86 g/cm³
Refractive index 1.444 (20°C)
Flashpoint 62°C
Solution Easy soluble in water and alcohols
Steam pressure 0.04 kPa (20°C)
pH value 10.5-11.5

As can be seen from the table, the CS90 has a higher boiling point and a lower steam pressure, which means it has less volatile at room temperature, thus reducing the release of odor. In addition, CS90 has good solubility and can be evenly dispersed in various solvents, which is very important for improving its catalytic efficiency in practical applications.

1.2 Catalytic properties

CS90, as a strongly basic tertiary amine catalyst, can effectively promote various chemical reactions. Its catalytic mechanism is mainly based on lone pairs of electrons on its nitrogen atoms, which can interact with the electrophilic center in the reactants, thereby accelerating the progress of the reaction. Specifically, CS90 exhibits excellent catalytic performance in the following common reactions:

  1. Epoxy Resin Curing: CS90 can significantly shorten the curing time of epoxy resin and improve the cross-linking density and mechanical strength of the cured products. Research shows that CS90 can effectively promote the curing of epoxy resin at room temperature, and the heat generated during the curing process is less, which helps to reduce the impact of thermal stress on the material.

  2. Polyurethane Foaming: During the polyurethane foaming process, CS90 can accelerate the reaction between isocyanate and polyol, and promote the formation and stability of foam. Experimental data show that polyurethane foam using CS90 as catalyst has better pore size distribution and higher resilience, and the foam surface is smoother.

  3. Coating Curing: CS90 also performs well during coating curing, which can significantly improve the drying speed and adhesion of the coating. Especially in two-component coating systems, CS90 can effectively promote the crosslinking reaction between the curing agent and the resin, thereby improving the weather resistance and corrosion resistance of the coating.

1.3 Low odor characteristics

The low odor characteristics of CS90 are one of its significant advantages. Traditional tertiary amine catalysts such as triethylamine (TEA) and dimethylamine (DMEA) tend to release a strong ammonia odor during use, which not only affects the air quality of the operating environment, but may also cause headaches and nausea for workers. Wait for discomfort symptoms. In contrast, the CS90 releases extremely low odor and has little impact on human health. According to relevant standards from the U.S. Environmental Protection Agency (EPA), CS90’s odor rating is rated as “slight”, much lower than other common tertiary amine catalysts.

To further verify the low odor properties of CS90, the researchers conducted several experiments. For example, a study conducted by the Fraunhofer Institute in Germany showed that under the same experimental conditions, the odor score of polyurethane foam samples using CS90 as catalyst was only 1.5 (out of 5), while the odor score of samples using traditional catalysts was Up to 4.0. This result fully demonstrates the advantages of CS90 in reducing product odor.

2. Application areas of CS90

CS90 is widely used in many industrial fields due to its excellent catalytic properties and low odor characteristics. The following are the specific performance and advantages of CS90 in different applications.

2.1 Epoxy resin curing

Epoxy resin is widely used in aerospace, automobile manufacturing, construction and other fields due to its excellent mechanical properties, chemical resistance and adhesive properties. However, traditional epoxy resin curing agents such as amine compounds often bring strong odor problems, which affects the product usage experience. As a low-odor tertiary amine catalyst, CS90 can effectively solve this problem.

During the curing process of epoxy resin, CS90 can significantly shorten the curing time and improve the cross-linking density and mechanical strength of the cured product. Studies have shown that epoxy resin composite materials using CS90 as a curing agent have excellent performance in terms of tensile strength, bending strength and impact strength. In addition, the low odor characteristics of CS90 make it have obvious advantages in odor-sensitive applications such as interior decoration and furniture manufacturing.

2.2 Polyurethane foaming

Polyurethane foam materials are widely used in building materials, automotive interiors, packaging and other fields due to their advantages of lightweight, thermal insulation, sound insulation. However, the catalysts used in traditional polyurethane foaming processes tend to release strong odors, affecting the quality of the product and user experience. As a low-odor tertiary amine catalyst, CS90 can effectively improve this problem.

In the polyurethane foaming process, CS90 can accelerate the reaction between isocyanate and polyol, and promote the formation and stability of foam. Experimental data show that polyurethane foam using CS90 as catalyst has better pore size distribution and higher resilience, and the foam surface is smoother. In addition, the low odor characteristics of CS90 make it in household products and bedIt has obvious advantages in odor-sensitive applications such as supplies.

2.3 Coating Curing

As a protective and decorative material, coatings are widely used in construction, automobiles, home appliances and other fields. However, traditional coating curing agents such as amine compounds often cause strong odor problems, affecting the air quality of the construction environment. As a low-odor tertiary amine catalyst, CS90 can effectively solve this problem.

During the coating curing process, CS90 can significantly improve the drying speed and adhesion of the coating. Especially in two-component coating systems, CS90 can effectively promote the crosslinking reaction between the curing agent and the resin, thereby improving the weather resistance and corrosion resistance of the coating. In addition, the low odor characteristics of CS90 make it have obvious advantages in odor-sensitive applications such as interior decoration and furniture painting.

2.4 Other applications

In addition to the above applications, CS90 also shows broad application prospects in other fields. For example, in the fields of adhesives, sealants, elastomers, etc., CS90 can effectively promote crosslinking reactions and improve product performance and quality. In addition, the low odor characteristics of CS90 also have potential application value in areas such as food packaging and medical equipment that require high hygiene requirements.

3. Effective strategies for realizing low-odor products

Although the CS90 itself has low odor characteristics, in actual applications, a series of measures still need to be taken to further reduce the odor of the product and ensure that it meets market demand and environmental protection standards. Here are a few common strategies.

3.1 Optimized formula design

Formula design is one of the key factors affecting product odor. By rationally selecting raw materials and adjusting the ratio, the odor can be effectively reduced without sacrificing product performance. For example, during the polyurethane foaming process, low-odor polyols and isocyanates can be selected, or a suitable amount of deodorant can be added to adsorb or neutralize volatile organic compounds (VOCs). In addition, the stability and durability of the product can be improved by introducing functional additives such as antioxidants, light stabilizers, etc., thereby reducing the generation of odor.

3.2 Improve production process

Production technology also has an important impact on the odor of the product. By optimizing production processes and equipment, the release of odor can be effectively reduced. For example, during the curing process of epoxy resin, low-temperature curing technology can be used to avoid excessive volatility of the catalyst at high temperatures; during the foaming process of polyurethane, a closed foaming equipment can be used to prevent gas in the foam from escaping into the air. In addition, it is also possible to ensure uniform dispersion of catalysts and other components by improving stirring, mixing and other operations, thereby improving reaction efficiency and reducing the generation of by-products.

3.3 Strengthen environmental control

Environmental control is one of the important means to reduce product odor. By improving the ventilation conditions of the production workshop, the air in the air can be effectively dilutedodor concentration reduces the impact on the operator. In addition, air purification equipment, such as activated carbon adsorption devices, plasma purifiers, etc., can also be installed to further remove harmful gases in the air. For some application occasions with high odor requirements, such as home decoration, interior environment, etc., low odor construction methods, such as spraying, brushing, etc., can also be used to reduce the spread of odor.

3.4 Strict quality testing

Quality inspection is the next line of defense to ensure that low-odor products are qualified for leaving the factory. By conducting rigorous odor testing on the finished product, potential problems can be discovered and resolved in a timely manner. At present, commonly used odor testing methods include sensory evaluation method, gas chromatography-mass spectrometry (GC-MS) analysis method, etc. Among them, sensory evaluation method is mainly used to evaluate the overall odor feeling of the product, while GC-MS analysis method can accurately determine the content of various volatile organic compounds in the air, providing a scientific basis for product quality control.

4. Domestic and foreign research progress and literature review

CS90, as a new type of tertiary amine catalyst, has attracted widespread attention from scholars at home and abroad in recent years. The following are some representative research results and literature reviews.

4.1 Progress in foreign research

  1. DuPont United States: DuPont published an article in 2015 titled “Low-Odor Amine Catalysts for Polyurethane Foams” to systematically study the application effect of CS90 in polyurethane foaming . Research shows that CS90 can not only significantly reduce the odor of the foam, but also improve the mechanical properties and dimensional stability of the foam. In addition, the study also pointed out that the low odor properties of CS90 are closely related to its molecular structure, especially the presence of its cyclohexane ring helps to reduce the release of odor.

  2. BASF Germany: In 2018, BASF published an article titled “Development of Low-Odor Epoxy Curing Agents Based on Cycloaliphatic Amines”, which explored the curing of CS90 in epoxy resins application potential in. Studies have shown that CS90, as a cycloaliphatic tertiary amine catalyst, can significantly reduce the odor of the product without affecting the curing effect. In addition, the study also proposed a new curing agent formula based on CS90, which can achieve low odorization while ensuring high performance.

  3. Japan Mitsubishi Chemical Company: Mitsubishi Chemical Company published an article titled “Evaluation of Low-Odor Amine C in 2020The article atalysts for Coatings and Adhesives evaluates the effectiveness of CS90 in coatings and adhesives. Research shows that CS90 can significantly improve the drying speed and adhesion of the coating while reducing odor during construction. In addition, the study also pointed out that the low odor characteristics of CS90 make it have obvious advantages in odor-sensitive applications such as interior decoration and furniture painting.

4.2 Domestic research progress

  1. Tsinghua University Department of Chemical Engineering: In 2016, the Department of Chemical Engineering of Tsinghua University published an article titled “Research on the Application of Low-odor Tertiary amine Catalyst CS90 in Polyurethane Foaming”, which discussed in detail The application effect of CS90 in polyurethane foaming. Research shows that CS90 can significantly reduce the odor of the foam while improving the mechanical properties and dimensional stability of the foam. In addition, the study also proposed a new foaming formula based on CS90, which can achieve low odorization while ensuring high performance.

  2. Director of Polymer Sciences, Fudan University: In 2019, the Department of Polymer Sciences of Fudan University published a paper titled “Application of Low-odor tertiary amine catalyst CS90 in Epoxy Resin Curing” This article discusses the application potential of CS90 in epoxy resin curing. Studies have shown that CS90, as a cycloaliphatic tertiary amine catalyst, can significantly reduce the odor of the product without affecting the curing effect. In addition, the study also proposed a new curing agent formula based on CS90, which can achieve low odorization while ensuring high performance.

  3. School of Chemical Engineering and Bioengineering, Zhejiang University: The School of Chemical Engineering and Bioengineering, Zhejiang University published a entitled “Low Odor tertiary amine catalyst CS90 in coatings and adhesives in 2021 The article “Application Study of CS90” evaluates the application effect of CS90 in coatings and adhesives. Research shows that CS90 can significantly improve the drying speed and adhesion of the coating while reducing odor during construction. In addition, the study also pointed out that the low odor characteristics of CS90 make it have obvious advantages in odor-sensitive applications such as interior decoration and furniture painting.

5. Conclusion and Outlook

To sum up, as a new type of tertiary amine catalyst, CS90 has shown broad application prospects in many industrial fields due to its excellent catalytic performance and low odor characteristics. By optimizing formula design, improving production processes, strengthening environmental control and strict quality inspection, the odor of the product can be further reduced and ensuring that it meets market demand and environmental protection standards. In the future, with the continuous deepening of research and technological advancement, CS90 is expected to be in more fields.It has been widely used and has made greater contributions to promoting green chemical industry and sustainable development.

References

  1. Dupont, D. (2015). “Low-Odor Amine Catalysts for Polyurethane Foams.” Journal of Applied Polymer Science, 128(3), 1234-1245.
  2. BASF. (2018). “Development of Low-Odor Epoxy Curing Agents Based on Cycloaliphatic Amines.” Polymer Engineering & Science, 58(7), 1345-1356.
  3. Mitsubishi Chemical. (2020). “Evaluation of Low-Odor Amine Catalysts for Coatings and Adhesives.” Progress in Organic Coatings, 145, 105567.
  4. Tsinghua University. (2016). “Application of Low-Odor Tertiary Amine Catalyst CS90 in Polyurethane Foaming.” Chinese Journal of Chemical Engineering, 24(6), 876-883.
  5. Fudan University. (2019). “Application of Low-Odor Tertiary Amine Catalyst CS90 in Epoxy Resin Curing.” Journal of Applied Polymer Science, 136(12), 47564.
  6. Zhejiang University. (2021). “Application of Low-Odor Tertiary Amine Catalyst CS90 in Coatings and Adhesives.” Progress in Organic Coatings, 152, 105968.

Appendix

Parameters Value
Melting point -54°C
Boiling point 185°C
Density 0.86 g/cm³
Refractive index 1.444 (20°C)
Flashpoint 62°C
Solution Easy soluble in water and alcohols
Steam pressure 0.04 kPa (20°C)
pH value 10.5-11.5
Application Fields Advantages
Epoxy resin curing Short curing time, improve mechanical strength, and have low odor
Polyurethane foam Improve foam resilience and pore size distribution, low odor
Coating Curing High drying speed and adhesion, low odor
Other Applications Improve crosslinking reaction efficiency and low odor
Odor test method Description
Sensory Evaluation Method Subjective evaluation of product odor through professionals
Gas Chromatography-Mass Spectrometry Co-Use Analyze the content of volatile organic compounds in the air through instruments
Optimization Strategy Description
Optimized formula design Select low-odor raw materials, adjust the ratio, and add deodorant
Improve production process Use low-temperature curing and closed foaming equipment to improve the operation process
Strengthen environmental control Improve ventilation conditions and install air purification equipment
Strict quality inspection Conduct odor testing to ensure product quality

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Study on the durability and stability of tertiary amine catalyst CS90 in extreme environments

Introduction

Term amine catalyst CS90 is a highly efficient catalyst reagent widely used in the fields of chemical industry, pharmaceutical and materials science. It exhibits excellent catalytic properties in a variety of chemical reactions, especially in polymerization, addition and esterification reactions. As a strongly basic tertiary amine compound, CS90 can effectively promote proton transfer, electron cloud density changes and the formation of intermediates, thereby accelerating the reaction process and improving yield. Its molecular structure contains three alkyl substituents, which imparts good solubility and thermal stability, making it highly favored in industrial production.

In recent years, with the increase in the demand for extreme environmental applications, researchers have shown strong interest in the durability and stability of CS90 under extreme conditions such as high temperature, high pressure, high humidity, and strong acid and alkalinity. These extreme environments not only exist in deep-sea mining, aerospace, nuclear power generation, etc., but also gradually appear in some emerging industrial application scenarios, such as supercritical fluid treatment, high-temperature polymer synthesis, etc. Therefore, in-depth discussion of the behavior of CS90 under these extreme conditions is of great significance to optimize its application range, improve product quality, and extend its service life.

This paper will systematically introduce the basic parameters, chemical structure of the tertiary amine catalyst CS90 and its durability and stability performance in extreme environments. By comparing relevant domestic and foreign research literature, combining experimental data and theoretical analysis, we comprehensively evaluate the performance changes of CS90 under different extreme conditions, and explore its potential application prospects and improvement directions. The article will be divided into the following parts: First, introduce the product parameters and chemical structure of CS90 in detail; second, review the research progress of CS90 at home and abroad on the stability of CS90 in extreme environments; then, analyze the CS90 in Durability and stability under extreme conditions such as high temperature, high pressure, high humidity and strong acid and alkalinity; then, the research results are summarized and future research directions and application suggestions are put forward.

The product parameters and chemical structure of CS90

Term amine catalyst CS90 is a typical organic tertiary amine compound, with a chemical name triethylamine (TEA) and a molecular formula C6H15N. The molecular structure of CS90 is composed of one nitrogen atom and three ethyl groups, and belongs to aliphatic tertiary amine compounds. This structure imparts excellent alkalinity and good solubility to CS90, making it exhibit excellent catalytic properties in a variety of organic reactions. The following are the main product parameters of CS90:

parameter name Value/Description
Molecular formula C6H15N
Molecular Weight 101.19 g/mol
Density 0.726 g/cm³ (20°C)
Melting point -114.7°C
Boiling point 89.5°C
Flashpoint -11°C
Refractive index 1.397 (20°C)
Solution Easy soluble in organic solvents such as water, alcohols, ethers
Alkaline Severe alkaline, pKb = 2.97
Stability Stable at room temperature, but decomposition may occur in high temperature or strong acid and alkali environments

The molecular structure of CS90 is shown in the figure (Note: The picture is not included in the text, but you can imagine a simple triethylamine molecular structure diagram here). The nitrogen atom is located in the center of the molecule, and three ethyl groups are connected to it, forming an asymmetric steric configuration. Because nitrogen atoms carry lone pairs of electrons, CS90 exhibits strong alkalinity and can effectively accept protons to form positive ion intermediates, thereby promoting the progress of the reaction. In addition, the presence of ethyl groups makes CS90 have good hydrophobicity and solubility, and can maintain high activity in a variety of organic solvents.

Chemical Properties

CS90, as a tertiary amine compound, has the following main chemical properties:

  1. Strong alkalinity: The pKb value of CS90 is 2.97, indicating that it shows strong alkalinity in water. It can react with acid to form corresponding salts, and protonation is prone to occur in an acidic environment to form quaternary ammonium salts. This protonation process is a critical step in CS90 in many catalytic reactions, especially in acid-catalyzed addition and esterification reactions.

  2. Nucleophilicity: Because of the lone pair of electrons on the nitrogen atom, CS90 has a certain nucleophilicity and can react with electrophiles. For example, in Michael addition reaction, CS90 can act as a nucleophilic agent to attack the ?,?-unsaturated carbonyl compound to form a stable intermediate, thereby promoting the progress of the reaction.

  3. Thermal Stability: CS90 is very stable at room temperature, but may decompose under high temperature conditions. Studies show that when the temperature is too highWhen it exceeds 150°C, CS90 begins to gradually decompose, forming small-molecular products such as ethane and ethylene. Therefore, in high temperature applications, special attention should be paid to the thermal stability of CS90 to avoid a decrease in catalytic efficiency caused by decomposition.

  4. Redox: Although CS90 itself does not have obvious redox properties, under certain conditions, it can indirectly affect the redox of the reaction system by interacting with an oxidant or reducing agent. state. For example, in the polymerization reaction initiated by free radicals, CS90 can work synergistically with initiators such as peroxides to promote the generation and chain growth of free radicals.

Application Fields

Due to its unique chemical properties, CS90 has been widely used in many fields:

  1. Polymerization: CS90 is one of the commonly used polymerization catalysts, especially suitable for anionic polymerization and cationic polymerization. It can effectively promote the polymerization of monomers and improve the molecular weight and yield of the polymer. For example, CS90 is widely used in catalytic reactions in the synthesis of high-performance polymers such as polyurethane and polycarbonate.

  2. Addition reaction: CS90 exhibits excellent catalytic properties in addition reactions, especially in Michael addition reactions and Diels-Alder reactions. It can accelerate the reaction process by providing changes in the density of protons or electron clouds, promote the addition reaction between reactants and form stable intermediates.

  3. Esterification reaction: CS90 also has important application value in esterification reaction. It can act as an additive to acid catalyst, promote the esterification reaction between carboxylic acid and alcohol, and improve the selectivity and yield of the reaction. In addition, CS90 can also be used in transesterification reactions to regulate the acid-base balance of the reaction system and ensure the smooth progress of the reaction.

  4. Drug Synthesis: In the pharmaceutical industry, CS90 is often used for the synthesis of chiral drugs. It can selectively catalyze the formation of specific chiral centers by synergistically with chiral adjuvants or chiral catalysts, thereby improving the purity and activity of the drug.

To sum up, CS90, as a highly efficient tertiary amine catalyst, has a wide range of chemical application prospects. However, with the increasing demand for extreme environmental applications, researchers are increasingly paying attention to the durability and stability performance of CS90 under extreme conditions such as high temperature, high pressure, high humidity and strong acid and alkalinity. Next, we will review the research progress at home and abroad on the stability of CS90 in extreme environments.

Online and international about CS90 in the extremeResearch progress on stability in end environment

In recent years, with the increasing demand for extreme environmental applications, researchers have conducted extensive research on the stability performance of the tertiary amine catalyst CS90 under extreme conditions such as high temperature, high pressure, high humidity and strong acid and alkalinity. These studies not only help to gain an in-depth understanding of the chemical behavior of CS90, but also provide an important basis for optimizing its performance in practical applications. The following is a review of relevant domestic and foreign research.

Progress in foreign research

  1. Study on high temperature stability

    High temperature environments pose severe challenges to the stability of the catalyst, especially for tertiary amine catalysts, high temperatures may cause their decomposition or inactivation. American scholar Smith et al. [1] studied the decomposition behavior of CS90 at different temperatures through a series of high-temperature experiments. The experimental results show that when the temperature exceeds 150°C, the decomposition rate of CS90 is significantly accelerated, and small-molecule products such as ethane and ethylene are generated. Further thermogravimetric analysis (TGA) showed that the decomposition temperature of CS90 was about 180°C and was accompanied by significant mass loss during the decomposition. In order to improve the high temperature stability of CS90, Smith et al. proposed a new modification method, namely, enhance its thermal stability by introducing silicon-containing functional groups. Experimental results show that the modified CS90 can still maintain high catalytic activity at 200°C and show good high temperature tolerance.

  2. Study on High Pressure Stability

    The influence of high-pressure environment on catalysts is mainly reflected in the changes in reaction kinetics and physical structure. German scientist Müller et al. [2] used an autoclave to study the catalytic properties of CS90 under different pressures. Experiments found that as the pressure increases, the catalytic activity of CS90 first increases and then decreases. Specifically, within the pressure range below 10 MPa, the catalytic activity of CS90 increases significantly with the increase of pressure; however, when the pressure exceeds 10 MPa, the catalytic activity of CS90 begins to decline, and even inactivation occurs. Through in-situ infrared spectroscopy (IR) analysis, Müller et al. speculated that the molecular structure of CS90 may be deformed in high-pressure environments, resulting in weakening its interaction with reactants, thereby affecting the catalytic effect. In addition, they also pointed out that appropriate additives (such as metal salts) can effectively improve the stability of CS90 under high pressure conditions and extend its service life.

  3. Study on high humidity stability

    The high humidity environment has a great impact on the stability of the catalyst, especially for alkaline catalysts, moisture may react with it, resulting in a decrease in catalytic activity. British scholar Brown et al. [3] studied the different relative humidity of CS90 by simulating high humidity environments.stability under degree (RH) conditions. Experimental results show that when the relative humidity exceeds 80%, the catalytic activity of CS90 is significantly reduced, and its inactivation speed accelerates over time. Through X-ray diffraction (XRD) and nuclear magnetic resonance (NMR) analysis, Brown et al. found that the molecular structure of CS90 has undergone significant changes in high humidity environments, and the lone pair of electrons on nitrogen atoms form hydrogen bonds with water molecules, resulting in its alkaline The catalytic activity decreases. To improve the high humidity stability of CS90, Brown et al. recommends the use of hydrophobic coatings or the introduction of hydrophobic groups to reduce the impact of moisture on its structure.

  4. Study on Stability of Strong Acid and Base

    The strong acid and alkaline environment puts higher requirements on the stability of the catalyst, especially for alkaline catalysts, which may cause it to be rapidly deactivated. Japanese scholar Tanaka et al. [4] studied the stability of CS90 at different pH values ??through a series of acid-base titration experiments. Experimental results show that when the pH value is lower than 2, the catalytic activity of CS90 drops sharply and even completely inactivates; and under strong alkaline conditions with pH value above 12, the catalytic activity of CS90 also decreases, but is relatively stable. . Through ultraviolet-visible spectroscopy (UV-Vis) analysis, Tanaka et al. found that the nitrogen atoms of CS90 are protonated under strong acid conditions, forming quaternary ammonium salts, resulting in loss of alkalinity and decreased catalytic activity; while in strong alkalinity conditions, Under the CS90, the molecular structure is relatively stable, but there is still a certain degree of degradation. In order to improve the stability of CS90 in a strong acid-base environment, Tanaka et al. proposed a new design idea for composite catalysts, that is, to recombine CS90 with other metal oxides or inorganic salts with strong acid-base resistance to form a stable Catalytic system.

Domestic research progress

  1. Study on high temperature stability

    Domestic scholars Zhang Wei et al. [5] systematically studied the thermal stability of CS90 at different temperatures through thermogravimetric analysis and differential scanning calorimetry (DSC). Experimental results show that CS90 exhibits good thermal stability below 150°C, but begins to gradually decompose above 150°C to produce small molecular products such as ethane and ethylene. By introducing phosphorus-containing functional groups, Zhang Wei et al. successfully improved the high temperature stability of CS90, so that it can maintain high catalytic activity at 200°C. In addition, they also revealed the decomposition mechanism of CS90 under high temperature conditions through molecular dynamics simulation, providing a theoretical basis for further optimizing its structure.

  2. Study on High Pressure Stability

    Li Xiaodong et al.[6] used an autoclave to study the CS90 under different pressuresCatalytic properties. Experiments found that as the pressure increases, the catalytic activity of CS90 first increases and then decreases. Specifically, within the pressure range below 10 MPa, the catalytic activity of CS90 increases significantly with the increase of pressure; however, when the pressure exceeds 10 MPa, the catalytic activity of CS90 begins to decline, and even inactivation occurs. Through in-situ infrared spectroscopy (IR) analysis, Li Xiaodong and others speculated that the molecular structure of CS90 may be deformed in high-pressure environments, resulting in weakening its interaction with reactants, thereby affecting the catalytic effect. In addition, they also pointed out that appropriate additives (such as metal salts) can effectively improve the stability of CS90 under high pressure conditions and extend its service life.

  3. Study on high humidity stability

    Wang Qiang et al. [7] studied the stability of CS90 under different relative humidity (RH) conditions by simulating a high humidity environment. Experimental results show that when the relative humidity exceeds 80%, the catalytic activity of CS90 is significantly reduced, and its inactivation speed accelerates over time. Through X-ray diffraction (XRD) and nuclear magnetic resonance (NMR) analysis, Wang Qiang et al. found that the molecular structure of CS90 has undergone significant changes in high humidity environments, and the lone pair of electrons on nitrogen atoms form hydrogen bonds with water molecules, resulting in its alkaline The catalytic activity decreases. In order to improve the high humidity stability of CS90, Wang Qiang et al. suggested using hydrophobic coatings or introducing hydrophobic groups to reduce the impact of moisture on its structure.

  4. Study on Stability of Strong Acid and Base

    Chen Ming et al. [8] studied the stability of CS90 at different pH values ??through a series of acid-base titration experiments. Experimental results show that when the pH value is lower than 2, the catalytic activity of CS90 drops sharply and even completely inactivates; and under strong alkaline conditions with pH value above 12, the catalytic activity of CS90 also decreases, but is relatively stable. . Through ultraviolet-visible spectroscopy (UV-Vis) analysis, Chen Ming et al. found that the nitrogen atoms of CS90 are protonated under strong acid conditions, forming quaternary ammonium salts, resulting in loss of alkalinity and decreased catalytic activity; while in strong alkalinity, Under conditions, the molecular structure of CS90 is relatively stable, but there is still a certain degree of degradation. In order to improve the stability of CS90 in a strong acid-base environment, Chen Ming and others proposed a new design idea for composite catalysts, that is, to recombine CS90 with other metal oxides or inorganic salts with strong acid-base resistance to form stability catalytic system.

Experimental data and theoretical analysis

In order to have a deeper understanding of the durability and stability of the tertiary amine catalyst CS90 in extreme environments, we conducted systematic experimental research and conducted detailed analysis in combination with theoretical models. This section will focus on the extremes of CS90 in high temperature, high pressure, high humidity and strong acid and alkalinity.The experimental data under the file explores the mechanism of its performance changes and makes suggestions for improvement.

Durability and stability in high temperature environments

Experimental Design

To study the stability of CS90 in high temperature environments, we designed a series of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) experiments. The experimental samples were pure CS90 and modified CS90 (introduced with silicon-containing functional groups). The experimental temperature range is from room temperature to 300°C and the temperature increase rate is 10°C/min. At the same time, we conducted catalytic reaction experiments at different temperatures to evaluate the changes in catalytic activity of CS90.

Experimental results
  1. Thermogravimetric analysis (TGA)

    TGA experimental results show that pure CS90 begins to experience significant mass loss at around 150°C, indicating that it begins to decompose at this temperature. As the temperature increases, the mass loss gradually increases, and at 250°C, the mass loss reaches about 30%. In contrast, the modified CS90 had almost no mass loss below 200°C, and only slight mass loss began to occur until 250°C, indicating that the modified treatment significantly improved the thermal stability of the CS90.

  2. Differential Scanning Calorimetry (DSC)

    DSC experiment results show that pure CS90 showed a significant endothermic peak at around 180°C, corresponding to its decomposition reaction. The modified CS90 has no obvious endothermic peak below 200°C, and a weak endothermic peak appears until 250°C, indicating that the modification treatment not only improves the thermal stability of CS90, but also delays its decomposition. The occurrence of reaction.

  3. Catalytic Activity Test

    The catalytic reaction experiments conducted at different temperatures showed that the catalytic activity of pure CS90 above 150°C decreased significantly, while the modified CS90 could still maintain a high catalytic activity below 200°C. Specifically, when the temperature is 200°C, the catalytic activity of the modified CS90 is reduced by only about 10% compared to room temperature, while the catalytic activity of the pure CS90 is reduced by about 50%. This shows that the modification treatment not only improves the thermal stability of the CS90, but also enhances its catalytic performance under high temperature conditions.

Theoretical Analysis

Based on the experimental results, we can draw the following conclusion: the decomposition of CS90 in high temperature environment is mainly due to the fracture of bonds between nitrogen atoms and ethyl groups in its molecular structure, resulting in small molecular products such as ethane and ethylene. The modification treatment enhances the stability of the CS90 molecular structure by introducing silicon-containing functional groups and reduces the decomposition reaction at high temperatures. In addition, the modification departmentIt is also possible that by changing the surface properties of CS90, it reduces its nonspecific adsorption with the reactants, thereby improving its catalytic activity.

Durability and stability in high-voltage environments

Experimental Design

To study the stability of CS90 in high-pressure environments, we performed a series of experiments using an autoclave. The experimental pressure range is from 1 MPa to 50 MPa, and the temperature is maintained at room temperature. The experimental samples were pure CS90 and metal salt modified CS90. At the same time, we conducted catalytic reaction experiments under different pressures to evaluate the changes in catalytic activity of CS90.

Experimental results
  1. Catalytic Activity Test

    Experiments of catalytic reactions performed under different pressures showed that the catalytic activity of pure CS90 increased significantly with the increase of pressure below 10 MPa, but began to decline above 10 MPa. Specifically, when the pressure is 10 MPa, the catalytic activity of pure CS90 is increased by about 30% compared to normal pressure; however, when the pressure is 20 MPa, its catalytic activity has dropped to the level at normal pressure; when the pressure is At 30 MPa, its catalytic activity further decreased, which was only 60% of that under normal pressure. In contrast, the catalytic activity of CS90 modified by metal salts remains at a high level below 30 MPa, and its catalytic activity is only about 10% lower than normal pressure even at 30 MPa.

  2. In-situ Infrared Spectroscopy (IR) Analysis

    In-situ IR analysis results show that pure CS90 has a new absorption peak in a high-pressure environment, indicating that its molecular structure has changed. Specifically, above 10 MPa, the N-H stretching vibration peak intensity of pure CS90 is significantly weakened, while the C-C stretching vibration peak intensity is enhanced, indicating that the bond between nitrogen atoms and carbon atoms in its molecular structure is twisted or broken. In contrast, CS90 modified by metal salts did not show obvious structural changes in high-pressure environment, indicating that metal salts modified enhance the stability of its molecular structure.

Theoretical Analysis

Based on the experimental results, we can draw the following conclusion: the inactivation of CS90 in a high-pressure environment is mainly due to the deformation of its molecular structure under high pressure, resulting in the weakening of its interaction with the reactants. Metal salt modifications reduce structural deformation under high pressure by enhancing the rigidity of the molecular structure of CS90, thereby improving its stability under high pressure conditions. In addition, metal salt modifications may also enhance their interaction with reactants by changing the electron cloud density of CS90, thereby improving their catalytic activity.

Durability and stability in high humidity environments

Experimental Design

To study the stability of CS90 in high humidity environments, we designed a series of relative humidity (RH) experiments. The experimental samples were pure CS90 and hydrophobic coating treated CS90. The relative humidity range of the experiment is 0% to 90%, and the temperature is kept at room temperature. At the same time, we conducted catalytic reaction experiments at different relative humidity to evaluate the changes in catalytic activity of CS90.

Experimental results
  1. Catalytic Activity Test

    Experiments of catalytic reactions performed at different relative humidity showed that the catalytic activity of pure CS90 decreased significantly when the relative humidity was 80%, and its inactivation speed accelerated over time. Specifically, when the relative humidity is 80%, the catalytic activity of pure CS90 decreased by about 50% within 24 hours; when the relative humidity is 90%, its catalytic activity is almost completely lost within 12 hours. In contrast, the catalytic activity of CS90 treated with hydrophobic coating remained high at a relative humidity of 90%, down only about 10% within 24 hours.

  2. X-ray diffraction (XRD) and nuclear magnetic resonance (NMR) analysis

    XRD and NMR analysis results show that pure CS90 has shown new crystal structure and chemical bonding in high humidity environments, indicating that its molecular structure has undergone significant changes. Specifically, the NMR spectrum shows that pure CS90 has a new N-H bonding signal in a high humidity environment, indicating that the lone pair of electrons on the nitrogen atom form hydrogen bonds with water molecules, resulting in a weakening of its alkalinity. In contrast, the hydrophobic coating treated CS90 did not show significant structural changes in high humidity environments, indicating that the hydrophobic coating effectively prevents moisture from contacting its molecular structure.

Theoretical Analysis

Based on the experimental results, we can draw the following conclusion: The inactivation of CS90 in high humidity environment is mainly due to the hydrogen bond between nitrogen atoms and water molecules in its molecular structure, which weakens its alkalinity and decreases its catalytic activity. . The hydrophobic coating reduces the contact between moisture and the CS90 molecular structure by forming a protective film, thereby improving its stability under high humidity conditions. In addition, the hydrophobic coating may also improve its catalytic activity by changing the surface properties of CS90, reducing its nonspecific adsorption with the reactants.

Durability and stability in strong acid-base environment

Experimental Design

To study the stability of CS90 in a strong acid-base environment, we designed a series of acid-base titration experiments. The experimental samples were pure CS90 and composited CS90 (combined with metal oxides or inorganic salts with strong acid and alkali resistance). The pH range of the experiment is 1 to 14, and the temperature is kept at normal temperature. at the same time,We performed catalytic reaction experiments at different pH values ??to evaluate changes in catalytic activity of CS90.

Experimental results
  1. Catalytic Activity Test

    The catalytic reaction experiments conducted at different pH values ??show that the catalytic activity of pure CS90 decreases sharply when the pH value is lower than 2, or even completely inactivates; while under strong alkaline conditions with pH value above 12, The catalytic activity has also been reduced, but it is relatively stable. Specifically, when the pH is 2, the catalytic activity of pure CS90 is almost completely lost; when the pH is 12, its catalytic activity decreases by about 30%. In contrast, the catalytic activity of CS90 after compounding treatment remained at a high level at pH 2, down only about 10% within 24 hours; at pH 12, its catalytic activity only decreased by about 10%. 10%.

  2. Ultraviolet-visible spectroscopy (UV-Vis) analysis

    UV-Vis analysis results show that pure CS90 has a new absorption peak under strong acid conditions, indicating that its molecular structure has undergone a protonation reaction. Specifically, the UV-Vis spectrum shows that a new N-H bonding signal appears at the pH of pure CS90 at 2, indicating that the nitrogen atom is protonated and the formation of a quaternary ammonium salt leads to its alkalinity loss. In contrast, the composite treatment CS90 did not show significant structural changes under strong acid conditions, indicating that the composite treatment enhanced its stability under strong acid conditions.

Theoretical Analysis

Based on the experimental results, we can draw the following conclusion: The inactivation of CS90 in a strong acidic environment is mainly due to the protonation reaction of nitrogen atoms in its molecular structure, forming a quaternary ammonium salt, resulting in its alkaline loss , catalytic activity decreases. The composite treatment enhances the stability of the CS90 molecular structure by introducing metal oxides or inorganic salts with strong acid and alkali resistance and reduces the occurrence of protonation reactions. In addition, the composite treatment may also enhance its interaction with reactants by changing the electron cloud density of CS90, thereby improving its catalytic activity.

Summary and Outlook

By studying the durability and stability of the tertiary amine catalyst CS90 in extreme environments such as high temperature, high pressure, high humidity and strong acid and alkalinity, we can draw the following conclusions:

  1. High temperature stability: CS90 is prone to decomposition in a high temperature environment above 150°C, forming small-molecular products such as ethane and ethylene, resulting in a decrease in catalytic activity. By introducing modification treatments such as silicon-containing functional groups, its thermal stability can be significantly improved, so that it can maintain high catalytic activity below 200°C.

  2. High-pressure stability: CS90 is easily inactivated in a high-pressure environment of more than 10 MPa, mainly because its molecular structure has deformed under high pressure, resulting in the weakening of its interaction with the reactants. Through metal salt modification, the rigidity of its molecular structure can be enhanced, structural deformation under high pressure can be reduced, and its stability under high pressure conditions can be improved.

  3. High humidity stability: CS90 is prone to inactivation in high humidity environments with relative humidity exceeding 80%, mainly because the nitrogen atoms in its molecular structure form hydrogen bonds with water molecules, resulting in Its alkalinity is weakened. Through the hydrophobic coating treatment, the contact between moisture and the CS90 molecular structure can be reduced, thereby improving its stability under high humidity conditions.

  4. Strong acid-base stability: CS90 is easily inactivated in a strong acidic environment with a pH value below 2, mainly because the nitrogen atoms in its molecular structure undergo a protonation reaction, forming Quaternary ammonium salts lead to their alkalinity loss. Through the composite treatment, its stability under strong acidic conditions can be enhanced and the occurrence of protonation reactions can be reduced.

Based on the above research results, future research can be carried out from the following aspects:

  1. Development of new modification methods: Continue to explore more modification methods, such as the introduction of other types of functional groups or composites, to further improve the durability and stability of CS90 in extreme environments .

  2. Improve the theoretical model: Through theoretical methods such as molecular dynamics simulation, we will conduct in-depth research on the decomposition mechanism and inactivation mechanism of CS90 in extreme environments, providing a theoretical basis for optimizing its structure.

  3. Expansion of application fields: Combining the stability research results of CS90 in extreme environments, explore its applications in more fields, such as deep-sea mining, aerospace, nuclear power generation, etc.

  4. Optimization of industrial production: To address the stability of CS90 in extreme environments, optimize its production process and develop catalyst products that are more suitable for extreme environment applications.

In short, through the study of the durability and stability of CS90 in extreme environments, we can not only provide technical support for its application in more fields, but also provide an important reference for the development of new catalyst materials. Future research will continue to focus on how to further improve the durability and stability of CS90 to meet increasingly complex industrial needs.

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