Dioctyltin oxide catalyst application

Dioctyltin oxide (chemical formula: C16H34OSn), usually abbreviated as DOTO, is an important organotin compound used as a chemical compound in the chemical industry. Efficient catalysts are widely used. It is known for its good catalytic activity, selectivity and stability, and plays a key role in polymer chemistry, esterification reactions and transesterification reactions.

Applications in polymer chemistry

In the field of polymer chemistry, dioctyltin oxide is particularly suitable for catalyzing the synthesis of polyesters. For example, in the synthesis process of polybutylene terephthalate (PBT), dioctyltin oxide can effectively accelerate the esterification reaction and improve the yield and quality of the polymer. Additionally, due to its lower toxicity compared to other organotin catalysts such as dibutyltin oxide, dioctyltin oxide becomes a more environmentally friendly choice, especially in applications where catalyst residues are strictly limited.

Production of PVC heat stabilizer

Dioctyltin oxide also plays an important role in the production of PVC (polyvinyl chloride) heat stabilizers. PVC easily decomposes at high temperatures, and adding heat stabilizers can prevent this decomposition and maintain the performance of PVC. As a catalyst, dioctyltin oxide can promote the effective synthesis of heat stabilizers, thus improving the quality and service life of PVC products.

Paint and coating industry

In the paint and coatings industry, dioctyltin oxide is used to enhance the properties of coatings. It can participate in the curing process of the coating as a catalyst, speed up the drying speed of the coating, and improve the hardness and weather resistance of the coating. This makes dioctyltin oxide one of the important additives for the production of high-performance paints and coatings.

ester exchange reaction

The transesterification reaction is crucial in the production of biodiesel, and dioctyltin oxide, as an efficient catalyst, can significantly increase the reaction rate and yield. In the transesterification reaction, vegetable oil or animal fat reacts with alcohol to generate biodiesel. The presence of dioctyltin oxide can effectively lower the reaction temperature, reduce the formation of by-products, and improve the purity of biodiesel.

Antioxidant production

In the production of antioxidants, dioctyltin oxide can also be used as a catalyst. Antioxidants are used to protect various materials from oxidative degradation and are widely used in plastics, rubber, lubricants and other fields. By using dioctyltin oxide as a catalyst, the synthesis efficiency of antioxidants can be improved and product quality can be ensured.

Conclusion

In summary, dioctyltin oxide has demonstrated outstanding performance in many fields of the chemical industry with its unique chemical properties and catalytic properties. Excellent application value. Whether facilitating polymer synthesis or increasing the efficiency of production of paints, coatings, biodiesel and antioxidants, dioctyltin oxide has proven itself to be an indispensable catalytic tool. With the advancement of science and technology and the improvement of environmental awareness, we are expected to see more innovative application scenarios in the future, allowing dioctyltin oxide to play a greater role in green chemistry and sustainable development.

Extended reading:

CAS:2212-32-0 – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

N,N-Dicyclohexylmethylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co ., LTD

bismuth neodecanoate/CAS 251-964-6 – Amine Catalysts (newtopchem.com)

stannous neodecanoate catalysts – Amine Catalysts (newtopchem.com)

polyurethane tertiary amine catalyst/Dabco 2039 catalyst – Amine Catalysts (newtopchem.com)

DMCHA – morpholine

N-Methylmorpholine – morpholine

Polycat 41 catalyst CAS10294-43-5 Evonik Germany – BDMAEE

Polycat DBU catalyst CAS6674-22-2 Evonik Germany – BDMAEE

The role of dioctyltin oxide in organic synthesis

Di-n-octyltin oxide (DOTO), chemical formula C16H34OSn, is an organotin compound used in organic synthesis He plays a variety of roles, especially in the field of catalysis, showing his unique advantages. As a class of metal-organic catalysts, dioctyltin oxide is favored for its high catalytic activity, good selectivity, and relatively low toxicity. The application and mechanism of dioctyltin oxide in organic synthesis will be discussed in detail below.

Catalysis

Esterification reaction

In organic synthesis, esterification reaction is one of the basic ways to construct ester compounds and is widely used in pharmaceutical synthesis, polymer manufacturing, perfume production and other fields. As a catalyst, dioctyltin oxide can significantly accelerate the esterification reaction between carboxylic acids and alcohols, improving yield and selectivity. Compared with traditional sulfuric acid or solid acid catalysts, dioctyltin oxide not only reduces the occurrence of side reactions, but also reduces the complexity of post-treatment, making it has obvious economic and environmental benefits in industrial production.

Polymerization reaction

For the synthesis of polyesters, especially the production of polyterephthalates (such as polyethylene terephthalate PET and polybutylene terephthalate PBT), dioctyltin oxide Demonstrate efficient catalytic ability. In these polymerization reactions, it can effectively promote the esterification and polycondensation steps, shorten the reaction time and increase the molecular weight of the polymer, thereby improving the physical and chemical properties of the product.

ester exchange reaction

In the production process of biodiesel, transesterification is a key step in converting vegetable oils or animal fats into fatty acid methyl esters. As a catalyst, dioctyltin oxide can reduce the reaction activation energy, improve conversion rate and selectivity, and at the same time reduce the impact on the environment, which is in line with the principles of green chemistry.

Reaction mechanism

During the catalytic process of dioctyltin oxide, the tin atom in the active center can form a coordination complex with the reactant, changing the electron cloud distribution of the reactant, thereby reducing the activation energy of the reaction and promoting the reaction. In esterification and transesterification reactions, dioctyltin oxide may form a transition state through interaction with alcoholic hydroxyl groups or carboxylic acid functional groups, accelerating the formation or breakage of ester bonds. In polymerization reactions, it may control the growth direction and length of the polymer chain through interaction with monomers or growing chain ends.

Environmental and health considerations

Although the application of dioctyltin oxide in organic synthesis provides many advantages, its potential ecotoxicity and human health risks cannot be ignored. As a class of organotin compounds, it may have adverse effects on aquatic ecosystems and is somewhat toxic to humans at high doses. Therefore, when using dioctyltin oxide as a catalyst, appropriate protective measures need to be taken to ensure its safe and environmentally friendly use.

Conclusion

The role of dioctyltin oxide in organic synthesis reflects its potential as an efficient catalyst, especially in esterification, polymerization and transesterification Waiting for key reactions. However, with the popularization of the concept of green chemistry, developing safer and more environmentally friendly catalyst systems and optimizing the use conditions of existing catalysts to reduce potential impacts on the environment and health are still important challenges faced by chemists. The research and application of dioctyltin oxide will continue to drive progress in the field of organic synthesis, while also prompting scientists to explore more sustainable chemical solutions.

Extended reading:

CAS:2212-32-0 – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

N,N-Dicyclohexylmethylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co ., LTD

bismuth neodecanoate/CAS 251-964-6 – Amine Catalysts (newtopchem.com)

stannous neodecanoate catalysts – Amine Catalysts (newtopchem.com)

polyurethane tertiary amine catalyst/Dabco 2039 catalyst – Amine Catalysts (newtopchem.com)

DMCHA – morpholine

N-Methylmorpholine – morpholine

Polycat 41 catalyst CAS10294-43-5 Evonik Germany – BDMAEE

Polycat DBU catalyst CAS6674-22-2 Evonik Germany – BDMAEE

The role of dioctyltin oxide in the plastics industry

Di-n-octyltin oxide (DOTO) plays a vital role in the plastics industry, especially in During the processing and stabilization of polyvinyl chloride (PVC). As a highly efficient organotin compound, it not only provides excellent thermal stability and processing performance, but also improves the physical and chemical properties of the product to a certain extent. The following are several key roles of dioctyltin oxide in the plastics industry, especially in the production of PVC products:

Heat stabilizer

PVC is prone to dehydrochlorination under heating conditions, leading to chain breakage and yellowing, seriously affecting its mechanical properties and appearance. As a thermal stabilizer, dioctyltin oxide can capture the released HCl and prevent it from further catalyzing the degradation reaction, thereby inhibiting the thermal degradation process of PVC. By providing a stable environment, it avoids further attack by HCl on the PVC molecular chain, extending the service life of the product and maintaining the transparency of the product.

Chain transfer agent

In addition to thermal stabilization, dioctyltin oxide also acts as a chain transfer agent. During the polymerization and processing of PVC, it can regulate the growth of the polymer chain, reduce the formation of unstable ends through chain transfer, thereby improving the fluidity of PVC, making the processing process smoother, and also helping to control the polymer properties. molecular weight distribution to optimize product performance.

Antioxidants

Dioctyltin oxide also shows certain antioxidant properties, which can resist the attack of hot oxygen and ultraviolet rays on PVC to a certain extent, improving the weather resistance and anti-aging capabilities of the product. This is particularly important for PVC products used outdoors, as they are often exposed to harsh environmental conditions.

steric hindrance effect

The long chain structure of dioctyltin oxide gives it good steric hindrance effect, which helps protect PVC molecules from damage by external factors. The steric hindrance effect can prevent harmful substances from directly contacting the PVC molecular chain, thereby acting as a physical barrier and further enhancing the stability of PVC.

Improve processing performance

In PVC processing, dioctyltin oxide can improve the plasticizing properties of the material, reduce the melting temperature, shorten the processing cycle, and improve production efficiency. This not only saves energy consumption, but also reduces production costs and improves economic benefits.

Structural Characteristics

The chemical formula of dioctyltin oxide is C16H34OSn. Its molecular structure contains two octyl chains and one tin oxide group. This special structure not only has good lipophilicity, but also can be evenly dispersed in the plastic matrix, ensuring the full play of its stabilizer function.

Application fields

Dioctyltin oxide is widely used in PVC soft products, hard products, and various PVC films, pipes, plates, wire and cable sheaths and other products. From PVC pipes used in construction to plastic packaging common in daily life, to automotive interior parts, dioctyltin oxide is one of the indispensable additives.

Safety and environmental protection

Although the application of dioctyltin oxide in the plastics industry has brought many benefits, its potential environmental and health risks also need to be taken into account. As an organotin compound, it may be harmful to aquatic life and is a potential threat to human health at high concentrations. As a result, the industry is constantly exploring safer and greener alternatives to reduce environmental impact while meeting increasingly stringent regulatory requirements.

In short, dioctyltin oxide is used in the plastics industry, especially in the production of PVC products, to ensure product quality, extend service life and improve processing Key ingredients for performance. However, its use also needs to be cautious to balance the relationship between economic benefits and environmental protection. With the development of green chemistry, finding more sustainable solutions will be an important trend in the plastics industry in the future.

Extended reading:

CAS:2212-32-0 – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

N,N-Dicyclohexylmethylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co ., LTD

bismuth neodecanoate/CAS 251-964-6 – Amine Catalysts (newtopchem.com)

stannous neodecanoate catalysts – Amine Catalysts (newtopchem.com)

polyurethane tertiary amine catalyst/Dabco 2039 catalyst – Amine Catalysts (newtopchem.com)

DMCHA – morpholine

N-Methylmorpholine – morpholine

Polycat 41 catalyst CAS10294-43-5 Evonik Germany – BDMAEE

Polycat DBU catalyst CAS6674-22-2 Evonik Germany – BDMAEE