How to use anti-yellowing agents in the sole to effectively improve the durability of outdoor shoes and prevent color changes

Anti-yellowing agent for soles: a secret weapon for outdoor shoes’ durability

1. Introduction: Why do shoes “change their faces”?

Have you ever encountered such an embarrassing scene? I just bought a brand new pair of white sneakers and wore them to the park for a walk, but when I came back I found that the soles had quietly turned yellow. What’s worse is that this color change is irreversible. No matter how much detergent or brush you use, it cannot restore it to its original whiteness and flawlessness. It’s like a friend who was originally energetic suddenly became dirty, making people want to ask: “What the hell happened?” In fact, this phenomenon has a professional name in the industry – the yellow soles of the shoe.

Yellowing soles is a common chemical reaction that usually occurs on soles made of rubber or plastic. Its culprit is the interaction between a series of complex environmental factors and material properties, such as ultraviolet radiation, high temperature oxidation, moisture invasion, etc. Especially for outdoor shoes that are often exposed to the sun, yellowing is almost an inevitable problem. Imagine that a pair of beautifully designed hiking shoes turned into “little yellow boots” due to long-term exposure to the sun. Isn’t it a bit ridiculous to cry?

However, with the advancement of technology, we finally have an effective means to fight this problem – anti-yellowing agent for soles. This magical chemical additive is like putting an invisible protective clothing on the soles of the shoe, which can effectively delay or even prevent the occurrence of yellowing. This article will explore in-depth the mechanism of action, application methods of anti-yellowing agents in the sole and how to improve the durability of outdoor shoes through it. At the same time, it will also combine relevant domestic and foreign literature to unveil the mystery of this field for you. If you are a shoe designer, manufacturer, or someone who simply likes to wear white shoes, this article will definitely benefit you a lot!


2. The “culprit” of yellowing soles: analyze the reasons from a scientific perspective

To understand the importance of anti-yellowing agents in the sole, we first need to figure out why the sole changes yellow. This is not a simple question, because it involves a series of complex chemical reactions and physical processes. Let’s go into the laboratory together and see who these “masters” are.

(I) UV rays: the culprit for “tanning” the soles

Ultraviolet rays (UV) are one of the main causes of yellowing of the sole. When rubber or plastic soles are exposed to sunlight, UV light can destroy its molecular structure, triggering a series of photochemical reactions. Specifically, ultraviolet rays can decompose certain organic components in the sole material, creating free radicals, which in turn leads to the degradation and discoloration of the material. This phenomenon is similar to the fact that fruits will gradually turn brown when exposed to the air after being cut, except that the “face change” speed of the soles of the shoe is much slower.

  • Metaphor: You can think of UV rays as a naughty kid who always likes to hold a magnifying glass to face your soles.”Bake. Although it may not be a big deal at the beginning, over time, the soles will be “baked” beyond recognition.

(II) Oxygen: a catalyst for “rusting” soles

In addition to ultraviolet rays, oxygen is also another important cause of yellowing. When the sole comes into contact with air, the unsaturated bonds in it will undergo an oxidation reaction, forming carbonyl compounds or other colored substances. The accumulation of these substances will gradually make the sole appear yellow or brown. Especially in high temperature environments, the oxidation reaction speed will be significantly accelerated, making the sole more likely to turn yellow.

  • Metaphor: If the sole is compared to a piece of metal, then oxygen is the bad guy who makes the metal rust. While the sole won’t really rust like iron, it does lose its original luster due to oxidation.

(III) Moisture and pollutants: Accomplices who accelerate yellowing

In addition to ultraviolet rays and oxygen, moisture and pollutants can also contribute to the yellowing of the sole. For example, moisture in a humid environment will penetrate into the sole material, causing more chemical reactions to occur; while pollutants such as dust and soil may be adsorbed on the sole surface, further aggravating the color changes.

  • Metaphor: Imagine that your sole is like a sponge, and every time you step into mud and water, you will absorb some impurities. These impurities not only make the soles look dirty, but may also become a catalyst for yellowing.

(IV) Quality issues of the material itself

Of course, in addition to the influence of the external environment, the characteristics of the sole material itself will also affect its anti-yellowing ability. For example, soles made of inferior rubber or undertreated plastics are often more likely to have yellowing problems. This is because these materials may contain more unstable components and are easily disturbed by external factors.

  • Metaphor: It’s like applying a wall with inferior paint. It may be beautiful at first, but it will peel and fade quickly. Similarly, low-quality sole materials cannot stand the test of time.

From the above analysis, it can be seen that yellowing of the sole is the result of a joint action of multiple factors. To completely solve this problem, we must find a solution that can fully resist these “culprits”. And this is the core value of anti-yellowing agent in the sole.


3. Anti-yellowing agent for soles: Principles and classification

Since we know the reasons for the yellowing of the sole, let’s learn how to use anti-yellowing agents to deal with these problems. Sole anti-yellowing agent is a special chemical additive. Its main function is to protect the sole material from yellowing by inhibiting or slowing down the various chemical reactions mentioned above. Next we willA detailed introduction to the working principle of anti-yellowing agent and its main classification.

(I) Working principle: Create a “golden bell cover” for the sole

The effects of anti-yellowing agents in the sole can be summarized into the following aspects:

  1. Absorb UV rays
    Anti-yellowing agents contain ingredients that can absorb ultraviolet rays, which will block UV light like an invisible umbrella to prevent it from causing damage to the sole material. This mechanism is similar to the protective effect of sunscreen on human skin.

  2. Catch free radicals
    Free radicals produced during oxidation are one of the key factors that lead to yellowing. Anti-yellowing agents can delay material aging and discoloration by capturing these free radicals, interrupting the chain reaction they trigger.

  3. Stable molecular structure
    Anti-yellowing agents can also enhance the molecular stability of sole materials, reduce the number of unsaturated bonds, and reduce their sensitivity to oxygen and other chemicals. It’s like putting a bulletproof vest on the sole to make it more sturdy and durable.

  4. Waterproof and stain-proof
    Some anti-yellowing agents also have certain waterproof and anti-fouling properties, which can reduce the impact of moisture and pollutants on the sole and further extend its service life.

(II) Category: Different needs correspond to different products

Depending on the purpose and effect, anti-yellowing agents in the sole can be divided into the following categories:

Type Features Scope of application
Light Stabilizer Mainly used to absorb ultraviolet rays and prevent photochemical reactions Commonly found in outdoor sports shoes, beach shoes, and other products that require long-term exposure to the sun
Antioxidants Focus on capturing free radicals and inhibiting oxidation reactions Widely used in various types of rubber and plastic soles
Thermal stabilizer Improve the heat resistance of the material and reduce discoloration caused by high temperature Shoes suitable for industrial shoes in high temperature environments or for special occasions
Comprehensive Anti-yellowing Agent It has multiple functions at the same time, and the overall effect is better Suitable for high-end brand footwear productsProduct

(III) Example of typical product parameters

The following are the specific parameters of several common sole anti-yellowing agents for reference:

name Ingredients Add ratio (wt%) Yellow-resistance grade Application Fields
UV-987 Trumped amine light stabilizers 0.5~1.0 Class A Outdoor sports shoes, hiking shoes
AO-200 Stealed phenolic antioxidants 0.3~0.8 Class B Daily casual shoes, children’s shoes
TS-600 Thermal stabilizer 0.2~0.5 Class C Industrial protective shoes, military shoes

It should be noted that different types of anti-yellowing agents may have cross-applications, and the specific choices should be adjusted according to actual needs and budget.


IV. Application methods of anti-yellowing agent for soles

After understanding the principles and classification of anti-yellowing agents, let’s talk about how to correctly apply them to sole production. This step is crucial because it directly determines the quality of the anti-yellowing effect.

(I) Mixing process: Even distribution is the key

Anti-yellowing agents are usually added to the sole material in powder or liquid form. In order to ensure that its effect is maximized, it is necessary to ensure the uniform distribution of the anti-yellowing agent in the material. Here are some common mixing process points:

  1. Premix phase
    Before mixing the raw materials, the anti-yellowing agent is fully stirred with part of the base material to form a premix. This can avoid the problem of excessive local concentration during subsequent processing.

  2. Temperature Control
    Pay attention to temperature control during mixing. Too high or too low temperatures may affect the effect of the anti-yellowing agent. Generally speaking, the optimal mixing temperature should be between 60 and 80°C.

  3. Time Management
    mixThe time should not be too short, otherwise the anti-yellowing agent may not be completely dispersed; but it should not be too long to avoid damaging the performance of the material itself.

(II) Forming process: Details determine success or failure

The molding process of the sole will also affect the effect of the anti-yellowing agent. Here are some things to note:

  1. Mold Cleaning
    Before injection molding or pressing, be sure to ensure that the mold is clean and without residue, otherwise it may affect the uniform distribution of the anti-yellowing agent.

  2. Cooling rate
    The cooling process after molding also needs to be strictly controlled. The cooling rate that is too fast or too slow may cause stress concentration, thereby weakening the effect of the anti-yellowing agent.

  3. Post-processing
    For certain special types of soles, additional post-treatment steps are required, such as spraying protective layers or surface polishing, to further enhance the anti-yellowing effect.


5. Domestic and foreign research progress: new breakthroughs in anti-yellowing technology

With the development of science and technology, new progress has been made in the research on anti-yellowing agents in the soles. Below, we will compare relevant domestic and foreign literature to see what innovative achievements are worth paying attention to in this field.

(I) Foreign research trends

In recent years, European and American countries have made many breakthroughs in the research and development of anti-yellowing agents for soles. For example, a US scientific research team has developed a new nano-scale light stabilizer. This product not only has excellent ultraviolet absorption capacity, but also can significantly improve the wear resistance and flexibility of sole materials. In addition, German scientists proposed an anti-yellowing solution based on biodegradable materials, which is both environmentally friendly and efficient, and has attracted widespread attention from the industry.

(II) Current status of domestic research

in the country, research on anti-yellowing agents for soles is also in full swing. A study from Tsinghua University shows that by optimizing the molecular structure of anti-yellowing agents, its stability under complex environmental conditions can be greatly improved. At the same time, South China University of Technology has successfully developed a multifunctional composite anti-yellowing agent that can achieve various functions such as light stability, antioxidant and waterproofing in a single formula.

(III) Future development trends

Looking forward, the development trend of anti-yellowing agents in soles mainly includes the following directions:

  1. Green and environmentally friendly
    As consumers’ environmental awareness increases, it will become an inevitable trend to develop more anti-yellowing agents based on natural raw materials or renewable resources.

  2. Intelligent
    Combining IoT technology and smart sensing devices, future anti-yellowing agents may have the ability to monitor and repair real-time, further improving the durability of the sole.

  3. Customization
    Providing personalized anti-yellowing solutions according to the needs of different users will be an important reflection of market competitiveness.


VI. Summary and Outlook: Keep every pair of shoes brilliant

Through the introduction of this article, we can see that anti-yellowing agents in the sole are not only an effective tool to solve the problem of yellowing of the sole, but also an important means to improve the durability and quality of outdoor shoes. Whether from the perspective of scientific principles or practical application, anti-yellowing agents have shown great potential and value.

Of course, there is still a lot of room to explore in this field. For example, how to further reduce costs, improve efficiency, and how to better meet personalized needs, we need to constantly explore and improve in practice. I believe that with the continuous advancement of technology, the anti-yellowing agent of the sole in the future will become more advanced and smarter, bringing more convenience and surprises to our lives.

After, I borrowed a famous saying to end this article: “Details determine success or failure.” The anti-yellow change of the sole seems to be just a small detail, but it directly affects the appearance and service life of the entire pair of shoes. Only by carefully doing every detail can we create truly satisfactory products. I hope every reader can get inspiration from it and jointly promote the development of this industry!

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Practical application cases of anti-yellowing agent in leather shoes maintenance, extending the service life of the shoes

Anti-yellowing agent for soles: a magical “doctor” that extends the lifespan of leather shoes

In daily life, a pair of leather shoes is like a loyal friend, accompanying us through every step of our life. However, as time goes by and environmentally friendly, the originally white or transparent soles often turn yellow and even age, which troubles many shoe lovers. At this time, the anti-yellowing agent of the sole became the “doctor” to save these shoes. This article will explore the practical application cases of anti-yellowing agents in leather shoes in the maintenance of shoes in depth, and reveal how it can extend the service life of shoes through scientific means.

What is anti-yellowing agent for soles?

Sole anti-yellowing agent is a chemical specifically designed to prevent the sole material from turning yellow due to oxidation or other chemical reactions. It is mainly used in materials that are prone to yellowing such as rubber, TPU (thermoplastic polyurethane), EVA (ethylene-vinyl acetate copolymer). Anti-yellowing agents maintain the color stability and physical properties of the sole by capturing free radicals, inhibiting photooxidation reactions, and reducing damage to the material by UV rays.

The working principle of anti-yellowing agent

  1. Free Radical Capture: Anti-yellowing agents can capture free radicals triggered by ultraviolet light or high temperatures, preventing them from further destroying polymer chains.
  2. Ultraviolet absorption: Some anti-yellowing agents also have ultraviolet absorption functions, which can convert harmful ultraviolet rays into heat energy and release them, thereby protecting the sole material from ultraviolet damage.
  3. Antioxidation: By providing additional electrons to the unstable molecular structure, anti-yellowing agents can effectively delay the oxidation process.

Practical application case analysis

To better understand the actual effects of anti-yellowing agents in the sole, let’s look at a few specific case studies:

Case 1: Application of sports shoe manufacturers

A well-known sports brand has introduced a new high-efficiency anti-yellowing agent in the production process of its new running shoes. After long-term testing, it was found that after using this anti-yellowing agent, even after being exposed to high-intensity sunlight for six months, the sole still maintained its original color and no obvious yellowing occurred. This not only improves the appearance quality of the product, but also enhances consumers’ purchasing confidence.

parameters Original Product Products with anti-yellowing agent
Yellow Index 4.5 1.2
Weathering time (hours) 800 >2000

Case 2: Maintenance of high-end business leather shoes

For business people who pursue high quality, a pair of neat leather shoes as new as possible is an important part of their professional image. A professional leather care company uses cleaners and maintenance solutions containing specific anti-yellowing ingredients to provide customers with regular maintenance services. The results show that the specially treated leather shoes have shown little signs of color changes or material aging within two years.

Test conditions Standard Control Group Processing Group
Light intensity (W/m²) 600 600
Temperature (°C) 40 40
Relative Humidity (%) 50 50
The degree of yellowing Significant Minimal

Domestic and foreign literature support and technological development

In recent years, research results on anti-yellowing agents in the soles have emerged one after another. For example, a study by the American Society of Materials (ASTM) showed that when used in a suitable proportion of hindered amine anti-yellowing agents (HALS) and benzotriazole type ultraviolet absorbers (UVAs), the weather resistance and yellowing resistance of synthetic rubber products can be significantly improved. In addition, German chemists have proposed a new nanocomposite anti-yellowing technology to use titanium dioxide nanoparticles to enhance the effect of traditional anti-yellowing agents. This innovation has been certified by multiple patents.

In China, the Department of Chemical Engineering of Tsinghua University and several shoemaking companies jointly developed a personalized anti-yellowing solution based on big data analysis. This solution intelligently recommends suitable anti-yellowing formulas based on different sole material characteristics and usage environments, which greatly facilitates the technological upgrade of small and medium-sized enterprises.

Summary and Outlook

To sum up, anti-yellowing agents for soles are not only an indispensable part of the modern shoemaking industry, but also one of the key factors to enhance consumer experience. From raw material selection to final product processing, every link is inseparable from scientific and reasonable anti-yellowing strategies. In the future, with the continuous advancement of new material technology and environmental protection concepts, I believe that anti-yellowing agents in the sole will become more efficient, safe and diversified, bringing more convenience and surprises to our lives.

As an ancient proverb says, “A journey of a thousand miles begins with a single step.” Having a pairGood shoes that last as long as new can not only allow us to go further, but also make our daily steps more firm and powerful. So, next time you pick up that bottle of inconspicuous anti-yellowing spray, remember how much hard work and wisdom of scientists are carried behind it!

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Anti-yellowing agent for soles is used in sandal production, significantly improving product appearance and durability

Anti-yellowing agent for soles: a secret weapon in sandal production

In the fashion industry, sandals are not only a seasonal necessity, but also an art form that expresses personality and taste. However, in daily use, the appearance of sandals may change irreversibly over time, especially the yellowing problem of the sole. This phenomenon not only affects the aesthetics of the product, but also may reduce consumers’ willingness to buy. In order to solve this problem, anti-yellowing agents in the sole came into being and became the “secret weapon” in sandal production. This article will conduct in-depth discussions on the basic principles, application methods, product parameters, and domestic and foreign research results of anti-yellowing agents to help readers fully understand how this magical chemical can make sandals shine for a lasting brilliance.

1. Causes and impacts of yellowing soles

(I) Definition and expression of yellowing

Yellow change of soles refers to the phenomenon that the sole material gradually changes in color under the long-term exposure to external factors such as light, heat, and oxygen. This change is usually manifested as the gradual yellowing of the white or light soles, and in severe cases, dark yellow or brown spots may appear, seriously affecting the appearance quality of the product. Yellowing is particularly prominent in common sole materials such as rubber, TPU (thermoplastic polyurethane), EVA (ethylene-vinyl acetate copolymer).

(II) The main reasons for yellowing

  1. Photooxidation
    Unsaturated bonds in sole materials will undergo photooxidation reaction under ultraviolet irradiation, resulting in a carbonyl compound with yellow characteristics. For example, aromatic isocyanate groups in TPU are very sensitive to ultraviolet rays and are prone to yellowing.

  2. Thermal aging effect
    During production and storage, high temperature environments can accelerate the aging process of sole materials, causing molecular chains to break and form yellow by-products.

  3. The Effect of Oxygen
    Oxygen acts as a catalyst for free radical reaction, which will cause oxidation and degradation of unstable structures in sole materials, thereby causing yellowing.

  4. Addant migration
    Plasticizers, stabilizers, or other additives used in certain sole formulations may migrate to the surface during use, reacting chemically after contact with air, resulting in yellowing.

(III) The impact of yellow change on sandals

The yellowing not only destroys the overall aesthetic of the sandals, but may also lead to consumers’ doubts about their durability and quality. For manufacturers, the yellowing problem not only increases the cost of rework, but also may damage the brand image. Therefore, solving the problem of yellowing has become an urgent need for the sandal industry to overcometechnical difficulties.


2. Principles and mechanism of anti-yellowing agent for soles

(I) Definition of anti-yellowing agent

Sole anti-yellowing agent is a class of chemical additives specially used to inhibit the yellowing of sole materials. They effectively extend the service life of sole materials and maintain their original color and performance by blocking or slowing down reaction channels such as photooxidation and thermal aging.

(II) Mechanism of action of anti-yellowing agent

  1. Absorb UV rays
    The UV absorber in the anti-yellowing agent can capture UV energy and convert it into harmless thermal energy to release it, thereby preventing the occurrence of photooxidation reactions.

  2. Catch free radicals
    Free radicals are important intermediates that cause yellowing. The antioxidant components in the anti-yellowing agent can neutralize free radicals by providing electrons, preventing the further development of chain reactions.

  3. Stable molecular structure
    Certain anti-yellowing agents can chemically react with unstable groups in sole materials to form a more stable structure and reduce the possibility of yellowing.

(III) Classification of anti-yellowing agents

Depending on the mechanism of action, anti-yellowing agents in the sole are mainly divided into the following categories:

Category Features Application Scenario
Ultraviolet absorber Absorb UV rays to prevent photooxidation Commonly used in outdoor sandals
Free Radical Scavenger Neutectic radicals and slow down oxidation reaction Sandals suitable for use in high temperature environments
Light Stabilizer Improve the light stability of the material Widely used in various sole materials
Antioxidants Stop oxidation and degradation, protect material properties Most used in indoor sandals

3. Product parameters of sole anti-yellowing agent

In order to better understand the practical application effects of anti-yellowing agents, the following lists some common product parameters and their significance:

Parameter name Description Reference value range Unit
Add ratio Recommended dosage of anti-yellowing agent in sole materials 0.5% – 2.0% Percent Mass
Heat resistance temperature Stable properties of materials under high temperature conditions 80°C – 150°C Celsius
Photostability The material’s yellowing resistance under ultraviolet rays ?90% Percent
Antioxidation Index The ability of materials to resist oxidative degradation ?85% Percent
Compatibility The degree of compatibility between anti-yellowing agent and sole material Excellent/good/poor Level

These parameters provide scientific evidence for manufacturers to help them choose anti-yellowing agents suitable for specific application scenarios.


IV. Application methods of anti-yellowing agents

(I) Adding method

The method of adding anti-yellowing agent directly affects its effect and uniformity. Commonly used methods of adding include:

  1. Direct mixing method
    The anti-yellowing agent is added directly to the sole material in powder or liquid form, and uniform dispersion is achieved by stirring or extrusion equipment.

  2. Masterbatch premix method
    Pre-made masterbatches for anti-yellowing agent and then mix them with the sole material in a certain proportion. This method can improve dispersion uniformity and operational convenience.

  3. Spraying treatment
    The surface of the molded sole is subjected to anti-yellowing agent spraying, which is suitable for occasions where local protection is required.

(II) Notes

  1. Control the amount of addition
    Excessive use of anti-yellowing agents may lead to decreased material properties such as increased hardness or reduced flexibility. Therefore, it must be strictly followedRecommended ratios are added.

  2. Ensure uniform distribution
    Uneven distribution will lead to poor anti-yellowing effect and even local yellowing.

  3. Avoid conflicts with other additives
    Some additives may have adverse reactions with anti-yellowing agents, affecting their performance. This should be fully considered when designing the formula.


5. Progress in domestic and foreign research

(I) Foreign research trends

In recent years, European and American countries have made significant progress in research on anti-yellowing agents in the field of soles. For example, BASF, Germany has developed a new light stabilizer that can effectively inhibit the yellowing of TPU soles under extreme conditions. DuPont, the United States, has launched a high-performance antioxidant that can greatly extend the service life of EVA soles.

In addition, Japan Toyo Textile Co., Ltd. proposed a composite anti-yellowing scheme, combining the advantages of ultraviolet absorbers and free radical scavengers to achieve comprehensive protection against various yellowing factors.

(II) Current status of domestic research

my country’s research on anti-yellowing agents in soles started late, but has developed rapidly in recent years. The School of Chemical Engineering of Zhejiang University has successfully developed a nanotechnology-based anti-yellowing agent, which is superior to traditional products in dispersion and stability. At the same time, the team of South China University of Technology has developed a highly efficient antioxidant for EVA sole materials, which significantly improves the yellowing resistance of the product.

(III) Comparative Analysis

Research Direction Foreign progress Domestic Progress
Ultraviolet protection New Light Stabilizer Nanoscale anti-yellowing agent
Oxidation Protection High-efficiency antioxidants Compound antioxidant
Comprehensive Protection Compound anti-yellowing agent Functional Modified Materials

It can be seen that domestic and foreign research has its own emphasis, but it gradually becomes consistent in functional improvement and practical application effects.


6. Economic benefits and environmental considerations of anti-yellowing agents

(I) Economic benefits

Using anti-yellowing agents can not only improve the appearance quality of sandals, but also extend the service life of the product, thereby reducing theRepair rate and complaint rate. According to statistics, the rational use of anti-yellowing agents can increase the market competitiveness of sandals by about 20%, bringing considerable economic benefits to the company.

(II) Environmental protection considerations

With the increasing global environmental awareness, the greening of anti-yellowing agents has become an important trend in the development of the industry. Many companies are working to develop low-toxic, degradable, environmentally friendly anti-yellowing agents to reduce negative impacts on the environment.


7. Conclusion

The wide application of anti-yellowing agents in soles has injected new vitality into the sandal industry. It not only solves the long-hacked yellowing problem, but also provides reliable guarantees for the appearance and durability of the product. In the future, with the continuous advancement of science and technology, anti-yellowing agents will make greater breakthroughs in functionalization and environmental protection, bringing consumers more high-quality sandals choices. As the saying goes, “Details determine success or failure”, and anti-yellowing agents are the key to the details.

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