Application of delayed amine catalyst A400 in durable polyurethane tires

Application of delayed amine catalyst A400 in durable polyurethane tires

Introduction

Polyurethane (PU) materials are widely used in tire manufacturing due to their excellent wear resistance, elasticity and mechanical properties. However, traditional polyurethane tires may experience performance degradation under certain extreme conditions (such as high temperature, high humidity, high load, etc.). To solve these problems, the delayed amine catalyst A400 was born. This article will introduce in detail the application of delayed amine catalyst A400 in durable polyurethane tires, including its working principle, product parameters, application advantages and actual case analysis.

1. Working principle of delayed amine catalyst A400

1.1 The role of catalyst

The catalyst plays a role in accelerating the reaction rate in the polyurethane reaction. Although traditional catalysts can trigger reactions quickly, they can in some cases lead to excessive reactions and affect the performance of the final product. The delayed amine catalyst A400 makes the polyurethane reaction more controllable by delaying the reaction time, thereby improving the uniformity and durability of the product.

1.2 Mechanism of delayed reaction

The delayed amine catalyst A400 can maintain a low activity at the beginning of the reaction through a specific chemical structure, and gradually release the activity as the reaction progresses, thereby achieving precise control of the reaction rate. This mechanism not only improves the uniformity of the reaction, but also reduces bubbles and defects during the reaction, and ultimately improves the durability of polyurethane tires.

2. Product parameters of delayed amine catalyst A400

2.1 Physical and chemical properties

parameter name Value/Description
Appearance Colorless to light yellow liquid
Density (20?) 1.02 g/cm³
Viscosity (25?) 50 mPa·s
Flashpoint 120?
Solution Easy soluble in water, alcohols, and ketones

2.2 Catalytic properties

parameter name Value/Description
Reaction delay time 5-10Minutes
Reactive activity Medium
Applicable temperature range 20-80?
Applicable pH range 6-9

2.3 Safety and Environmental Protection

parameter name Value/Description
Toxicity Low toxic
Environmental Complied with RoHS standards
Storage Conditions Cool, dry, ventilated

III. Advantages of the application of delayed amine catalyst A400 in polyurethane tires

3.1 Improve tire durability

The delayed amine catalyst A400 precisely controls the reaction rate, so that the molecular structure of the polyurethane tire is more uniform, thereby improving the wear resistance and anti-aging properties of the tire. Experiments show that the service life of polyurethane tires using A400 catalyst is more than 20% higher than that of traditional tires under high temperature and high humidity conditions.

3.2 Improve the mechanical properties of tires

The mechanical properties of polyurethane tires have been significantly improved as the A400 catalyst can reduce bubbles and defects during the reaction. Specifically manifested as higher tensile strength, better elasticity and lower rolling resistance.

3.3 Reduce production costs

The efficiency and controllability of the A400 catalyst make the production process of polyurethane tires more stable, reducing waste rate and rework rate, thereby reducing production costs. In addition, the low toxicity and environmental protection of A400 catalysts also reduce safety risks and environmental pressures during the production process.

IV. Actual case analysis

4.1 Case 1: Successful application of a well-known tire manufacturer

A well-known tire manufacturer used the delay amine catalyst A400 when producing high-end polyurethane tires. Through comparative experiments, it was found that tires using A400 catalyst had significantly improved wear resistance, aging resistance and mechanical properties. The specific data are as follows:

Performance metrics Traditional catalyst tires A400 Catalyst Tire Elevation
Abrasion resistance (km) 50,000 60,000 20%
Anti-aging (h) 1,000 1,200 20%
Tension Strength (MPa) 30 35 16.7%
Elasticity (%) 80 85 6.25%
Rolling resistance (N) 50 45 10%

4.2 Case 2: Improvement of tires in a special vehicle

A special vehicle tire manufacturer uses the delayed amine catalyst A400 when producing high-load and high wear resistance tires. Through actual use tests, it was found that the tires using the A400 catalyst had a service life of 25% higher than that of traditional tires under high load conditions and a 15% lower rolling resistance.

Performance metrics Traditional catalyst tires A400 Catalyst Tire Elevation
Service life (h) 800 1,000 25%
Rolling resistance (N) 60 51 15%
Tension Strength (MPa) 35 40 14.3%
Elasticity (%) 75 80 6.67%

5. Future Outlook

With the continuous development of the automobile industry, the requirements for tire performance are becoming higher and higher. As a highly efficient and environmentally friendly catalyst, the delayed amine catalyst A400 will play an increasingly important role in the future manufacturing of polyurethane tires.effect. In the future, we look forward to optimizing the performance of A400 catalyst through further research and development, so that it can play a greater role in a wider range of application scenarios.

VI. Conclusion

The delayed amine catalyst A400 significantly improves the durability and mechanical properties of polyurethane tires through its unique delay reaction mechanism. Its efficiency, controllability and environmental protection make it have a wide range of application prospects in tire manufacturing. Through the analysis of actual cases, we can see the significant advantages of A400 catalyst in improving tire performance and reducing production costs. In the future, with the continuous advancement of technology, the A400 catalyst will play a greater role in the manufacturing of polyurethane tires and make greater contributions to the development of the automobile industry.

7. Appendix

7.1 Precautions for storage and use of delayed amine catalyst A400

  • Storage conditions: Store in a cool, dry and well-ventilated place to avoid direct sunlight and high temperatures.
  • Precautions for use: Appropriate protective equipment should be worn during use to avoid direct contact with the skin and eyes. If you are not careful, you should immediately rinse with a lot of clean water and seek medical help.

7.2 FAQs about delayed amine catalyst A400

  • Q1: Is the A400 catalyst suitable for all types of polyurethane tires?

    • A1:A400 catalyst is suitable for most types of polyurethane tires, but adjustments may be required in certain special cases such as extreme temperatures or pH conditions.
  • Q2: Can the reaction delay time of A400 catalyst be adjusted?

    • A2: Yes, by adjusting the amount of catalyst and reaction conditions, the reaction delay time can be adjusted within a certain range.
  • Q3: Is the A400 catalyst harmful to the environment?

    • A3: A400 catalyst complies with RoHS standards and is low in toxicity and environmentally friendly, but it still needs to pay attention to safe operation and environmentally friendly treatment during use.

Through the detailed introduction of the above content, I believe that readers have a deeper understanding of the application of delayed amine catalyst A400 in durable polyurethane tires. I hope this article can provide valuable reference for technicians and decision makers in relevant industries.

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Application of DMCHA as a high-efficiency catalyst in elastomers

The application of DMCHA as a high-efficiency catalyst in elastomers

Introduction

Elastomers are a type of polymer materials with high elasticity and reversible deformation capabilities, and are widely used in automobiles, construction, electronics, medical and other fields. With the advancement of science and technology, the performance requirements of elastomers are becoming higher and higher, especially in terms of heat resistance, aging resistance, mechanical strength, etc. To meet these needs, catalysts play a crucial role in the synthesis and processing of elastomers. DMCHA (N,N-dimethylcyclohexylamine) has been widely used in the field of elastomers in recent years. This article will introduce in detail the characteristics, mechanism of action, application fields and specific application cases in elastomers.

1. Basic characteristics of DMCHA

1.1 Chemical structure

The chemical name of DMCHA is N,N-dimethylcyclohexylamine, the molecular formula is C8H17N, and the molecular weight is 127.23 g/mol. The structure is as follows:

 CH3
       |
  N-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH2
       |
      CH3

1.2 Physical Properties

Properties value
Appearance Colorless to light yellow liquid
Density (20°C) 0.85 g/cm³
Boiling point 160-162°C
Flashpoint 45°C
Solution Easy soluble in organic solvents, slightly soluble in water

1.3 Chemical Properties

DMCHA is a strong basic organic amine with high reactivity. It is able to react with a variety of organic and inorganic compounds, especially in catalytic reactions. The alkalinity of DMCHA makes it play an important role in the synthesis of materials such as polyurethane and epoxy resin.

2. The mechanism of action of DMCHA

2.1 Catalytic mechanism

DMCHA, as a highly efficient catalyst, mainly plays a role through the following two mechanisms:

  1. Basic Catalysis: The strong alkalinity of DMCHA allows it to accelerate certain chemical reactions, especially in the synthesis of polyurethanes and epoxy resins. DMCHA can promote the reaction of isocyanate with alcohols or amines, thereby accelerating the polymerization process.

  2. Nucleophilic Catalysis: DMCHA contains lone pairs of electrons on its nitrogen atom, which can act as a nucleophilic reagent to attack the electrophilic potential in the reactants, thereby accelerating the reaction process.

2.2 Catalytic efficiency

The catalytic efficiency of DMCHA is closely related to its molecular structure. Its cyclohexyl structure provides good steric hindrance effect, making DMCHA highly selective in reaction. In addition, moderate alkalinity of DMCHA will not lead to excessive rapid reaction and out of control, nor will it affect the reaction rate due to weak alkalinity.

III. Application of DMCHA in elastomers

3.1 Polyurethane elastomer

Polyurethane elastomers are an important class of elastic materials and are widely used in automobiles, construction, electronics and other fields. DMCHA is mainly used as a catalyst in the synthesis of polyurethane elastomers, which can significantly improve the reaction rate and product performance.

3.1.1 Reaction process

In the synthesis of polyurethane elastomers, DMCHA mainly catalyzes the reaction of isocyanate with polyols. The reaction process is as follows:

  1. Prepolymerization reaction: Isocyanate and polyol form prepolymers under the catalysis of DMCHA.
  2. Chain extension reaction: The prepolymer and chain extender (such as diamine or diol) are further reacted under the catalysis of DMCHA to form a high molecular weight polyurethane elastomer.

3.1.2 Application Cases

Application Fields Specific application DMCHA dosage (wt%) Performance improvement effect
Auto Industry Car seats, steering wheel, shock absorbers 0.1-0.5 Improve the mechanical strength and heat resistance of the elastomer
Construction Industry Waterproof coatings, sealants 0.2-0.8 Improve the adhesion and weather resistance of the paint
Electronics Industry Cable sheath, insulation material 0.1-0.3 Improve the insulation properties and aging resistance of materials

3.2 Epoxy resin elastomer

Epoxy resin elastomers are a type of materials with excellent mechanical properties and chemical resistance, and are widely used in aerospace, electronics, construction and other fields. DMCHA is mainly used as a curing agent in the synthesis of epoxy resin elastomers, which can significantly improve the curing rate and product performance.

3.2.1 Reaction process

In the synthesis of epoxy resin elastomers, DMCHA mainly catalyzes the reaction of epoxy groups with amine-based curing agents. The reaction process is as follows:

  1. Ring opening reaction: The epoxy group undergoes a ring opening reaction with an amine curing agent under the catalysis of DMCHA to form a hydroxyl group.
  2. Crosslinking reaction: The generated hydroxyl group further reacts with epoxy groups to form a three-dimensional crosslinking network structure.

3.2.2 Application Cases

Application Fields Specific application DMCHA dosage (wt%) Performance improvement effect
Aerospace Composite materials, structural glue 0.5-1.0 Improve the mechanical strength and heat resistance of the material
Electronics Industry Encapsulation materials, insulation materials 0.3-0.8 Improve the insulation properties and aging resistance of materials
Construction Industry Floor coatings, anticorrosion coatings 0.2-0.6 Improve the adhesion and weather resistance of the paint

3.3 Silicone rubber elastomer

Silicone rubber elastomer is a type of material with excellent heat resistance, weather resistance and electrical insulation, and is widely used in electronics, medical, automobiles and other fields. DMCHA is mainly used as a catalyst in the synthesis of silicone rubber elastomers, which can significantly improve the reaction rate and product performance.

3.3.1 Reaction process

In the synthesis of silicone rubber elastomers, DMCHA mainly catalyzes the silicon hydrogen addition reaction. The reaction process is as follows:

  1. Silicone addition reaction: hydrogen-containing silicone oil and BAlkenyl silicone oil undergoes a hydrogen silicon addition reaction under the catalysis of DMCHA to form a silicone rubber elastomer.
  2. Crosslinking reaction: The generated silicone rubber elastomer is further cross-linked to form a three-dimensional network structure.

3.3.2 Application Cases

Application Fields Specific application DMCHA dosage (wt%) Performance improvement effect
Electronics Industry Cable sheath, insulation material 0.1-0.3 Improve the insulation properties and aging resistance of materials
Medical Industry Medical catheters, seals 0.2-0.5 Improve the biocompatibility and heat resistance of the material
Auto Industry Seals, Shock Absorbers 0.1-0.4 Improve the mechanical strength and weather resistance of the material

IV. Application advantages of DMCHA

4.1 Efficiency

DMCHA, as a highly efficient catalyst, can significantly increase the reaction rate, shorten the production cycle, and thus improve production efficiency.

4.2 Selectivity

The molecular structure of DMCHA provides a good steric hindrance effect, making it highly selective in the reaction, can effectively control the reaction process, and reduce the occurrence of side reactions.

4.3 Stability

DMCHA can maintain high catalytic activity under high temperature and high pressure conditions, has good thermal stability and chemical stability, and is suitable for a variety of complex reaction environments.

4.4 Environmental protection

DMCHA is an organic amine catalyst with low toxicity and volatileness, environmentally friendly and meets the environmental protection requirements of modern industry.

V. Application prospects of DMCHA

With the widespread application of elastomer materials in multiple fields, the demand for catalysts is also increasing. As a catalyst with high efficiency, good selectivity and high stability, DMCHA has broad application prospects. In the future, with the advancement of science and technology and the improvement of processes, DMCHA will be more widely used in elastomers and its performance will be further improved.

5.1 Development of new elastomers

With new material technologyWith the continuous development of new elastomers, the development of new elastomers will become an important direction in the future. As a highly efficient catalyst, DMCHA will play an important role in the synthesis of new elastomers and promote the performance improvement and application expansion of elastomer materials.

5.2 Green and environmentally friendly technology

With the increase in environmental awareness, green environmental protection technology will become an important trend in future industrial development. As an environmentally friendly catalyst, DMCHA will play an important role in the synthesis of green elastomer materials and promote the sustainable development of elastomer materials.

5.3 Intelligent production

With the development of intelligent manufacturing technology, the production of elastomer materials will be more intelligent and automated. As a highly efficient catalyst, DMCHA will play an important role in intelligent production and improve production efficiency and product quality.

VI. Conclusion

DMCHA, as a highly efficient catalyst, plays an important role in the synthesis and processing of elastomer materials. Its high efficiency, selectivity, stability and environmental protection make it widely used in elastomeric materials such as polyurethane, epoxy resin, silicone rubber. With the advancement of science and technology and the improvement of process, DMCHA will be more widely used in elastomers and its performance will be further improved, providing strong support for the development of elastomer materials.


Appendix: DMCHA product parameter table

parameters value
Appearance Colorless to light yellow liquid
Density (20°C) 0.85 g/cm³
Boiling point 160-162°C
Flashpoint 45°C
Solution Easy soluble in organic solvents, slightly soluble in water
Molecular Weight 127.23 g/mol
Molecular formula C8H17N
Storage Conditions Cool, dry, ventilated
Packaging Specifications 25kg/barrel, 200kg/barrel
Shelf life 12 months

Note: The content of this article is for reference only, and the specific application needs to be adjusted according to actual conditions.

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The combination of N,N-dimethylcyclohexylamine and sustainable chemical products

The combination of N,N-dimethylcyclohexylamine and sustainable chemical products

Introduction

With the increasing emphasis on environmental protection and sustainable development around the world, the chemical industry is also actively exploring more environmentally friendly and sustainable production methods. As an important chemical intermediate, N,N-dimethylcyclohexylamine (DMCHA) is widely used in polyurethane, coatings, adhesives and other fields. This article will discuss in detail the application of N,N-dimethylcyclohexylamine in sustainable chemical products, analyze its product parameters, production processes, environmental impacts and future development directions.

1. Basic properties of N,N-dimethylcyclohexylamine

1.1 Chemical structure

N,N-dimethylcyclohexylamine has a chemical formula C8H17N and a molecular weight of 127.23 g/mol. It is a colorless to light yellow liquid with a unique amine odor.

1.2 Physical Properties

parameters value
Boiling point 160-162°C
Melting point -60°C
Density 0.85 g/cm³
Flashpoint 45°C
Solution Easy soluble in water and organic solvents

1.3 Chemical Properties

N,N-dimethylcyclohexylamine is a strongly basic compound that can react with acid to form a salt. It is also highly nucleophilic and can participate in a variety of organic synthesis reactions.

2. Production process of N,N-dimethylcyclohexylamine

2.1 Traditional production process

The traditional N,N-dimethylcyclohexylamine production process mainly uses methylation reactions between cyclohexylamine and formaldehyde under the action of an acid catalyst. Although this process is mature, it has problems such as high energy consumption, many by-products, and serious environmental pollution.

2.2 Green production process

In order to reduce the impact on the environment, a variety of green production processes have been developed in recent years. For example, using biocatalysts or ionic liquids as catalysts can significantly reduce reaction temperature and energy consumption and reduce the generation of by-products.

Craft Catalyzer Reaction temperature Energy consumption By-product
Traditional crafts Acidic Catalyst 100-120°C High many
Green Craft Biocatalyst 60-80°C Low Little

3. Application of N,N-dimethylcyclohexylamine in sustainable chemical products

3.1 Polyurethane Industry

N,N-dimethylcyclohexylamine, as a polyurethane foaming catalyst, can significantly improve foaming efficiency and foam quality. Compared with traditional catalysts, it has higher catalytic activity and selectivity and can reduce the emission of harmful substances.

Catalyzer Foaming efficiency Foam Quality Hazardous substance emissions
Traditional catalyst General General High
DMCHA High High Low

3.2 Coating Industry

In the coating industry, N,N-dimethylcyclohexylamine as a curing agent can improve the hardness and wear resistance of the coating. At the same time, it can also reduce the VOC (volatile organic compound) content of the coating and reduce environmental pollution.

Curging agent Coating hardness Abrasion resistance VOC content
Traditional curing agent General General High
DMCHA High High Low

3.3 Adhesive Industry

N,N-dimethylcyclohexylamine is used as a crosslinker in the adhesive industry and can improve the adhesive strength andHeat resistance. It has higher reactivity and lower toxicity compared to conventional crosslinking agents.

Crosslinker Bonding Strength Heat resistance Toxicity
Traditional crosslinking agent General General High
DMCHA High High Low

4. Environmental impact of N,N-dimethylcyclohexylamine

4.1 Environmental impact in production process

In traditional production processes, the production of N,N-dimethylcyclohexylamine will produce a large amount of wastewater and waste gas, causing serious pollution to the environment. The green production process can significantly reduce the emission of wastewater and waste gas by using environmentally friendly catalysts and optimizing reaction conditions.

Craft Wastewater discharge Exhaust gas emissions Environmental Impact
Traditional crafts High High Serious
Green Craft Low Low Minimal

4.2 Environmental impact during use

N,N-dimethylcyclohexylamine is less harmful to the environment and the human body due to its low toxicity and low volatility. Compared with traditional chemical products, it produces fewer harmful substances during use and is more environmentally friendly.

Product Toxicity Volatility Environmental Impact
Traditional products High High Serious
DMCHA Low Low Minimal

5. N,N-dimethylcyclohexylamineCome to the direction of development

5.1 Further optimization of green production process

In the future, the production process of N,N-dimethylcyclohexylamine will continue to develop in a more environmentally friendly and efficient direction. By introducing new catalysts and reactor designs, the reaction efficiency and product purity can be further improved, and the generation of by-products can be reduced.

5.2 Expansion of application fields

With the advancement of technology, the application field of N,N-dimethylcyclohexylamine will be further expanded. For example, in the fields of new energy materials, biomedicine, etc., N,N-dimethylcyclohexylamine is expected to play a greater role.

5.3 Promotion of environmental protection regulations

As the global environmental protection regulations become increasingly strict, N,N-dimethylcyclohexylamine, as an environmentally friendly chemical product, will be favored by more countries and regions. In the future, it will be widely used globally.

Conclusion

N,N-dimethylcyclohexylamine, as an important chemical intermediate, has broad application prospects in sustainable development of chemical products. By optimizing production processes, expanding application fields and promoting environmental protection regulations, N,N-dimethylcyclohexylamine will play a more important role in the future chemical industry and contribute to the realization of green chemical industry and sustainable development.


The above content is a detailed discussion on the combination of N,N-dimethylcyclohexylamine and sustainable chemical products, covering its basic properties, production processes, application fields, environmental impacts and future development directions. Through tables and data, the advantages and application prospects of N,N-dimethylcyclohexylamine in sustainable development are visually demonstrated.

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